FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387132810> ?p ?o ?g. }

• W4387132810 endingPage "387" @default.
• W4387132810 startingPage "387" @default.
• W4387132810 abstract "Luminescent diimine-Pt(IV) complexes [Pt(N^N)(Me)2(PhSe)2], (N^N = 2,2′-bipyridine (bpy, 1b), 1,10-phenanthroline (phen, 2b), and 4,4′-dimethyl-2,2′-bipyridine (Me2bpy, 3b), PhSe− = phenyl selenide were prepared and identified using multinuclear (1H, 13C{1H} and 77Se{1H}) NMR spectroscopy. The PhSe− ligands were introduced through oxidative addition of diphenyl diselenide to the non-luminescent Pt(II) precursors [Pt(N^N)(Me)2], N^N = (bpy, 1a), (phen, 2a), (Me2bpy, 3a), to give the luminescent Pt(IV) complexes 1b–3b. The UV-vis absorption spectra of 1b–3b are characterised by intense bands in the range 240–330 nm. We assigned them to transitions of essentially π−π* character with small metal and PhSe− ligand contributions with the help of TD-DFT (time-dependent density functional theory) calculations. The weak long-wavelength bands in the range 350–475 nm are of mixed ligand-to-metal charge transfer (L’MCT) (n(Se)→d(Pt)/intra-ligand charge transfer (IL’CT) (n(Se)→π*(Ph) or π(Ph)→π*(Ph))/ligand-to-ligand’ charge transfer (LL’CT) (L = N^N, L’ = PhSe−, M = Pt and n = lone pair) character. The Pt(IV) complexes showed broad emission bands in the solid state at 298 and 77 K, peaking at 560–595 nm with a blue shift upon cooling. Structured emission bands were obtained in the range 450–600 nm, with the maxima depending on the N^N ligands and the solvent polarity (CH2Cl2 vs. dimethyl sulfoxide (DMSO) and aqueous tris(hydroxymethyl)aminomethane hydrochloride (tris-HCl) buffer). The emissions originate from essentially ligand-centred triplet states (3LC) with mixed IL’CT/L’MCT contributions as concluded from the DFT calculation. Such dominating PhSe contributions to the emissive states are unprecedented in the world of luminescent diimine-Pt(IV) complexes." @default.
• W4387132810 created "2023-09-29" @default.
• W4387132810 creator A5001288879 @default.
• W4387132810 creator A5033842944 @default.
• W4387132810 creator A5046763720 @default.
• W4387132810 creator A5068690063 @default.
• W4387132810 creator A5092960315 @default.
• W4387132810 date "2023-09-28" @default.
• W4387132810 modified "2023-10-18" @default.
• W4387132810 title "Luminescent Diimine-Pt(IV) Complexes with Axial Phenyl Selenide Ligands" @default.
• W4387132810 cites W1904586211 @default.
• W4387132810 cites W1941555263 @default.
• W4387132810 cites W1974893883 @default.
• W4387132810 cites W1981652420 @default.
• W4387132810 cites W1984614201 @default.
• W4387132810 cites W1991892007 @default.
• W4387132810 cites W1992008849 @default.
• W4387132810 cites W1996052202 @default.
• W4387132810 cites W1998945486 @default.
• W4387132810 cites W1999371754 @default.
• W4387132810 cites W2001368228 @default.
• W4387132810 cites W2014361643 @default.
• W4387132810 cites W2021231925 @default.
• W4387132810 cites W2023271753 @default.
• W4387132810 cites W2023491464 @default.
• W4387132810 cites W2041417902 @default.
• W4387132810 cites W2044974762 @default.
• W4387132810 cites W2051963424 @default.
• W4387132810 cites W2053309831 @default.
• W4387132810 cites W2059036179 @default.
• W4387132810 cites W2073723347 @default.
• W4387132810 cites W2092039511 @default.
• W4387132810 cites W2106824077 @default.
• W4387132810 cites W2121397176 @default.
• W4387132810 cites W2135653847 @default.
• W4387132810 cites W2143981217 @default.
• W4387132810 cites W2152322059 @default.
• W4387132810 cites W2162102008 @default.
• W4387132810 cites W2166519016 @default.
• W4387132810 cites W2187027385 @default.
• W4387132810 cites W2316501784 @default.
• W4387132810 cites W2320879464 @default.
• W4387132810 cites W2335270489 @default.
• W4387132810 cites W2408531307 @default.
• W4387132810 cites W2493307949 @default.
• W4387132810 cites W2503250420 @default.
• W4387132810 cites W2556788732 @default.
• W4387132810 cites W2593539434 @default.
• W4387132810 cites W2605122291 @default.
• W4387132810 cites W2756400977 @default.
• W4387132810 cites W2771932273 @default.
• W4387132810 cites W2781879318 @default.
• W4387132810 cites W2783189413 @default.
• W4387132810 cites W2783349815 @default.
• W4387132810 cites W2786633572 @default.
• W4387132810 cites W2789898844 @default.
• W4387132810 cites W2799609422 @default.
• W4387132810 cites W2803453985 @default.
• W4387132810 cites W2885417431 @default.
• W4387132810 cites W2905057937 @default.
• W4387132810 cites W2914307347 @default.
• W4387132810 cites W2933040001 @default.
• W4387132810 cites W2974078791 @default.
• W4387132810 cites W2989585017 @default.
• W4387132810 cites W3007513152 @default.
• W4387132810 cites W3014038085 @default.
• W4387132810 cites W3017693523 @default.
• W4387132810 cites W3035917359 @default.
• W4387132810 cites W3037820384 @default.
• W4387132810 cites W3092872930 @default.
• W4387132810 cites W3096465300 @default.
• W4387132810 cites W3149507045 @default.
• W4387132810 cites W3159320217 @default.
• W4387132810 cites W3162554180 @default.
• W4387132810 cites W3180411979 @default.
• W4387132810 cites W3201519143 @default.
• W4387132810 cites W4220756996 @default.
• W4387132810 cites W4283778500 @default.
• W4387132810 doi "https://doi.org/10.3390/inorganics11100387" @default.
• W4387132810 hasPublicationYear "2023" @default.
• W4387132810 type Work @default.
• W4387132810 citedByCount "0" @default.
• W4387132810 crossrefType "journal-article" @default.
• W4387132810 hasAuthorship W4387132810A5001288879 @default.
• W4387132810 hasAuthorship W4387132810A5033842944 @default.
• W4387132810 hasAuthorship W4387132810A5046763720 @default.
• W4387132810 hasAuthorship W4387132810A5068690063 @default.
• W4387132810 hasAuthorship W4387132810A5092960315 @default.
• W4387132810 hasBestOaLocation W43871328101 @default.
• W4387132810 hasConcept C116569031 @default.
• W4387132810 hasConcept C148869448 @default.
• W4387132810 hasConcept C155647269 @default.
• W4387132810 hasConcept C161790260 @default.
• W4387132810 hasConcept C170493617 @default.
• W4387132810 hasConcept C178790620 @default.
• W4387132810 hasConcept C185592680 @default.
• W4387132810 hasConcept C192562407 @default.
• W4387132810 hasConcept C2776303508 @default.

• next