Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387140541> ?p ?o ?g. }
- W4387140541 endingPage "401" @default.
- W4387140541 startingPage "393" @default.
- W4387140541 abstract "Deep eutectic solvents (DESs) have emerged as novel alternatives to common solvents and VOCs. Their employment as electrolytes in batteries has been an area of intense research. In this context, understanding changes in the physicochemical properties of DESs in the presence of Li salts becomes of utmost importance. Solvatochromic probes have the potential to gauge such changes. It is reported herein that one such UV–vis molecular absorbance probe, Reichardt’s betaine dye 33, effectively manifests changes taking place in a DES Glyceline composed of H-bond accepting salt choline chloride and H-bond donor glycerol in a 1:2 molar ratio, as salt LiCl is added. The lowest energy intramolecular charge–transfer absorbance band of this dye exhibits a 17 nm hypsochromic shift as up to 3.0 molal LiCl is added to Glyceline. The estimated ETN parameter shows a linear increase with the LiCl mole fraction. Spectroscopic responses of betaine dye 33, N,N-diethyl-4-nitroaniline and 4-nitroaniline are used to assess empirical Kamlet–Taft parameters of dipolarity/polarizability (π*), H-bond-donating acidity (α) and H-bond-accepting basicity (β) as a function of LiCl concentration in Glyceline. LiCl addition to Glyceline results in an increase in α and no change in π* and β. It is proposed that the added lithium interacts with the oxygen of the –OH functionalities on the glycerol rendering of the solvent with increased H-bond-donating acidity. It is observed that pyrene, a popular fluorescence probe of solvent polarity, does respond to the addition of LiCl to Glyceline, however, the change in pyrene response starts to become noticeable only at higher LiCl concentrations (mLiCl ≥ 1.5 m). Reichardt’s betaine dye is found to be highly sensitive and versatile in gauging the physicochemical properties of DESs in the presence of LiCl." @default.
- W4387140541 created "2023-09-29" @default.
- W4387140541 creator A5012487013 @default.
- W4387140541 creator A5059737090 @default.
- W4387140541 creator A5084085000 @default.
- W4387140541 date "2023-09-28" @default.
- W4387140541 modified "2023-10-18" @default.
- W4387140541 title "Effective Recognition of Lithium Salt in (Choline Chloride: Glycerol) Deep Eutectic Solvent by Reichardt’s Betaine Dye 33" @default.
- W4387140541 cites W1967410318 @default.
- W4387140541 cites W1975115962 @default.
- W4387140541 cites W1983195328 @default.
- W4387140541 cites W1986108898 @default.
- W4387140541 cites W1994139775 @default.
- W4387140541 cites W2013221003 @default.
- W4387140541 cites W2029807337 @default.
- W4387140541 cites W2055914734 @default.
- W4387140541 cites W2057003691 @default.
- W4387140541 cites W2084461567 @default.
- W4387140541 cites W2089049959 @default.
- W4387140541 cites W2090391132 @default.
- W4387140541 cites W2099214293 @default.
- W4387140541 cites W2114896354 @default.
- W4387140541 cites W2126852238 @default.
- W4387140541 cites W2319128214 @default.
- W4387140541 cites W2321005010 @default.
- W4387140541 cites W2329665471 @default.
- W4387140541 cites W2342352727 @default.
- W4387140541 cites W2586865643 @default.
- W4387140541 cites W2803001896 @default.
- W4387140541 cites W2809508345 @default.
- W4387140541 cites W2922266326 @default.
- W4387140541 cites W2952431217 @default.
- W4387140541 cites W3081614836 @default.
- W4387140541 cites W3086599044 @default.
- W4387140541 cites W3110668392 @default.
- W4387140541 cites W3111802430 @default.
- W4387140541 cites W3186467804 @default.
- W4387140541 cites W3215137280 @default.
- W4387140541 cites W4206332573 @default.
- W4387140541 cites W4361219432 @default.
- W4387140541 doi "https://doi.org/10.3390/liquids3040024" @default.
- W4387140541 hasPublicationYear "2023" @default.
- W4387140541 type Work @default.
- W4387140541 citedByCount "0" @default.
- W4387140541 crossrefType "journal-article" @default.
- W4387140541 hasAuthorship W4387140541A5012487013 @default.
- W4387140541 hasAuthorship W4387140541A5059737090 @default.
- W4387140541 hasAuthorship W4387140541A5084085000 @default.
- W4387140541 hasBestOaLocation W43871405411 @default.
- W4387140541 hasConcept C112887158 @default.
- W4387140541 hasConcept C121332964 @default.
- W4387140541 hasConcept C148093993 @default.
- W4387140541 hasConcept C17814232 @default.
- W4387140541 hasConcept C178790620 @default.
- W4387140541 hasConcept C179104552 @default.
- W4387140541 hasConcept C18168003 @default.
- W4387140541 hasConcept C185592680 @default.
- W4387140541 hasConcept C2777248517 @default.
- W4387140541 hasConcept C2777327210 @default.
- W4387140541 hasConcept C2778375661 @default.
- W4387140541 hasConcept C2780026712 @default.
- W4387140541 hasConcept C2780371645 @default.
- W4387140541 hasConcept C2780471494 @default.
- W4387140541 hasConcept C2780990938 @default.
- W4387140541 hasConcept C32909587 @default.
- W4387140541 hasConcept C43617362 @default.
- W4387140541 hasConcept C62520636 @default.
- W4387140541 hasConcept C67218372 @default.
- W4387140541 hasConcept C75473681 @default.
- W4387140541 hasConcept C91881484 @default.
- W4387140541 hasConcept C98015330 @default.
- W4387140541 hasConceptScore W4387140541C112887158 @default.
- W4387140541 hasConceptScore W4387140541C121332964 @default.
- W4387140541 hasConceptScore W4387140541C148093993 @default.
- W4387140541 hasConceptScore W4387140541C17814232 @default.
- W4387140541 hasConceptScore W4387140541C178790620 @default.
- W4387140541 hasConceptScore W4387140541C179104552 @default.
- W4387140541 hasConceptScore W4387140541C18168003 @default.
- W4387140541 hasConceptScore W4387140541C185592680 @default.
- W4387140541 hasConceptScore W4387140541C2777248517 @default.
- W4387140541 hasConceptScore W4387140541C2777327210 @default.
- W4387140541 hasConceptScore W4387140541C2778375661 @default.
- W4387140541 hasConceptScore W4387140541C2780026712 @default.
- W4387140541 hasConceptScore W4387140541C2780371645 @default.
- W4387140541 hasConceptScore W4387140541C2780471494 @default.
- W4387140541 hasConceptScore W4387140541C2780990938 @default.
- W4387140541 hasConceptScore W4387140541C32909587 @default.
- W4387140541 hasConceptScore W4387140541C43617362 @default.
- W4387140541 hasConceptScore W4387140541C62520636 @default.
- W4387140541 hasConceptScore W4387140541C67218372 @default.
- W4387140541 hasConceptScore W4387140541C75473681 @default.
- W4387140541 hasConceptScore W4387140541C91881484 @default.
- W4387140541 hasConceptScore W4387140541C98015330 @default.
- W4387140541 hasFunder F4320320721 @default.
- W4387140541 hasIssue "4" @default.
- W4387140541 hasLocation W43871405411 @default.
- W4387140541 hasOpenAccess W4387140541 @default.
- W4387140541 hasPrimaryLocation W43871405411 @default.