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- W4387142746 abstract "Non-oxidative photo-desulfurization of Dibenzothiophene (DBT) was studied using pure Fe2O3-Al2O3 and its sub-driven nanocomposites with polystyrene (PS). The incorporation of inorganic composite with PS was done through two routes. In the first one, particles of PS were ex-situ coupled with those of Fe2O3-Al2O3 nanocomposite via using ultrasonic waves while in the second the inorganic nanocomposite was in-situ added in the aqueous phase during PS preparation stage. Proper analytical techniques were employed to determine the physicochemical properties of the prepared structures. The impact of PS content (10-50%), in the prepared composites, on the sulfur removal efficiency was investigated and optimum operating conditions were optimized. The photocatalyst which contained 30% PS and was prepared via ex-situ route (denoted as px30/NC70) could exhibit a maximum sulfur removal 94.9%. On the other side, the photocatalyst which had same composition but was prepared via in-situ technique (labeled as pi30/NC70) could reveal less desulfurization activity, particularly 84%. The increased performance by px30/NC70 over the other photocatalyst could be referred to the differences in their textural properties. The prior-stated sulfur removal percentages were detected at 1 g/L (catalyst dose), 500 W (power of light source) and 30 min (reaction time) as optimum operating conditions. The noticed desulfurization exploit by px30/NC70 was found to be eight-fold higher than that of Fe2O3-Al2O3." @default.
- W4387142746 created "2023-09-29" @default.
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- W4387142746 date "2023-11-01" @default.
- W4387142746 modified "2023-10-16" @default.
- W4387142746 title "Highly efficient polystyrene / Fe2O3-Al2O3 heterojunction photocatalyst for non-oxidative DBT desulfurization at visible light irradiation" @default.
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- W4387142746 doi "https://doi.org/10.1016/j.cherd.2023.09.041" @default.
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