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- W4387160466 abstract "The environmentally benign synthesis of indoline boronic esters, especially through a way of arylboration to alkenes, remains a challenge due to the use of transition metals or high temperature conditions. We describled a photoinduced metal-free arylboration of unactivated alkenes for the synthesis of indoline boronic esters and 1,2,3,4-tetrahydroquinoline boronic ester in good yields. This approach showed good compatibility and great efficiency for a range of allylphenylamines as well as alkylamine. Remarkably, this transformation also suggested that the base is not necessary for photosensitizer-free diboron reagent-mediated mild generation of aryl radical. Furthermore, compared to previously reported methods, this approach is mild and environmentally benign." @default.
- W4387160466 created "2023-09-30" @default.
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- W4387160466 date "2023-09-29" @default.
- W4387160466 modified "2023-09-30" @default.
- W4387160466 title "Photoinduced Metal-Free Arylboration of Unactivated Alkenes Synthesis of Indoline Boronic Ester" @default.
- W4387160466 doi "https://doi.org/10.1055/a-2184-5014" @default.
- W4387160466 hasPublicationYear "2023" @default.
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