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- W4387189877 abstract "Dicarboxylic acids have a wide range of applications in the polymer industry to construct valuable materials. Photocatalysis has recently emerged as an efficient and sustainable strategy to generate dicarboxylic acids. However, photocatalytic dicarboxylation with CO2 is mainly limited to unsaturated bonds, and the dicarboxylation of C–C single bonds still remains a challenge. Herein, we report a photocatalytic dicarboxylation of C–C single bonds in strained rings with CO2 units via consecutive photo-induced electron transfer (ConPET). It is also the first photocatalytic reductive ring-opening reaction of cyclobutanes. Notably, this transition-metal-free protocol exhibits good functional group tolerance, broad substrate scope, facile scalability, and easy product derivatizations. Moreover, diacids can easily be derivatized to main-chain liquid crystalline polyesters." @default.
- W4387189877 created "2023-09-30" @default.
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- W4387189877 date "2023-09-01" @default.
- W4387189877 modified "2023-10-18" @default.
- W4387189877 title "Photocatalytic dicarboxylation of strained C–C bonds with CO2 via consecutive visible-light-induced electron transfer" @default.
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- W4387189877 doi "https://doi.org/10.1016/j.cclet.2023.109138" @default.
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