Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387221640> ?p ?o ?g. }
- W4387221640 abstract "Abstract Depolymerization of condensation polymers by chemolysis often suffers from the large usage of solvents and homogeneous catalysts such as acids, bases, and metal salts. The catalytic efficiency of heterogeneous catalysts is largely constrained by the poor interfacial contact between solid catalysts and solid plastics below melting points. We report here our discovery of autogenous heterogeneous catalyst layer on polyethylene terephthalate surfaces during the generally believed homogeneous catalytic depolymerization process. Inspired by the “contact mass” concept in industrial chlorosilane production, we further demonstrate that the construction of plastic‐catalyst solid‐solid interfaces enables solvent‐free depolymerization of polyethylene terephthalate by vapor phase methanolysis at relatively low temperatures. Trace amounts of earth‐abundant element (zinc) introduced by electrostatic adsorption is sufficient for catalyzing the depolymerization. The concept of plastic‐catalyst contact mass interfacial catalysis might inspire new pathways for tackling plastic waste problems." @default.
- W4387221640 created "2023-10-01" @default.
- W4387221640 creator A5011819622 @default.
- W4387221640 creator A5021774788 @default.
- W4387221640 creator A5056412989 @default.
- W4387221640 creator A5065333564 @default.
- W4387221640 date "2023-10-13" @default.
- W4387221640 modified "2023-10-15" @default.
- W4387221640 title "Solvent‐Free Depolymerization of Plastic Waste Enabled by Plastic‐Catalyst Interfacial Engineering" @default.
- W4387221640 cites W1598562144 @default.
- W4387221640 cites W1973419721 @default.
- W4387221640 cites W1979475041 @default.
- W4387221640 cites W1994056495 @default.
- W4387221640 cites W1998003033 @default.
- W4387221640 cites W2031630069 @default.
- W4387221640 cites W2044637028 @default.
- W4387221640 cites W2070227796 @default.
- W4387221640 cites W2108888484 @default.
- W4387221640 cites W2136615766 @default.
- W4387221640 cites W2294707565 @default.
- W4387221640 cites W2444352686 @default.
- W4387221640 cites W2556583147 @default.
- W4387221640 cites W2653069682 @default.
- W4387221640 cites W2737217596 @default.
- W4387221640 cites W2801649829 @default.
- W4387221640 cites W2886581168 @default.
- W4387221640 cites W2898725133 @default.
- W4387221640 cites W2899097190 @default.
- W4387221640 cites W2975990275 @default.
- W4387221640 cites W2981503372 @default.
- W4387221640 cites W3012199788 @default.
- W4387221640 cites W3012481340 @default.
- W4387221640 cites W3015207233 @default.
- W4387221640 cites W3017199550 @default.
- W4387221640 cites W3030230209 @default.
- W4387221640 cites W3043008983 @default.
- W4387221640 cites W3044029393 @default.
- W4387221640 cites W3044174595 @default.
- W4387221640 cites W3048799828 @default.
- W4387221640 cites W3087333805 @default.
- W4387221640 cites W3094505816 @default.
- W4387221640 cites W3097559636 @default.
- W4387221640 cites W3103334439 @default.
- W4387221640 cites W3111345093 @default.
- W4387221640 cites W3133455371 @default.
- W4387221640 cites W3155838129 @default.
- W4387221640 cites W3191870946 @default.
- W4387221640 cites W4207021652 @default.
- W4387221640 cites W4220770890 @default.
- W4387221640 cites W4292865836 @default.
- W4387221640 cites W4298006419 @default.
- W4387221640 cites W4298088356 @default.
- W4387221640 cites W4301599872 @default.
- W4387221640 cites W4305040595 @default.
- W4387221640 cites W4321748779 @default.
- W4387221640 cites W4362661829 @default.
- W4387221640 cites W4367599093 @default.
- W4387221640 cites W4379374966 @default.
- W4387221640 doi "https://doi.org/10.1002/ange.202309949" @default.
- W4387221640 hasPublicationYear "2023" @default.
- W4387221640 type Work @default.
- W4387221640 citedByCount "0" @default.
- W4387221640 crossrefType "journal-article" @default.
- W4387221640 hasAuthorship W4387221640A5011819622 @default.
- W4387221640 hasAuthorship W4387221640A5021774788 @default.
- W4387221640 hasAuthorship W4387221640A5056412989 @default.
- W4387221640 hasAuthorship W4387221640A5065333564 @default.
- W4387221640 hasConcept C127413603 @default.
- W4387221640 hasConcept C159985019 @default.
- W4387221640 hasConcept C161790260 @default.
- W4387221640 hasConcept C178790620 @default.
- W4387221640 hasConcept C185592680 @default.
- W4387221640 hasConcept C188027245 @default.
- W4387221640 hasConcept C192562407 @default.
- W4387221640 hasConcept C2779751980 @default.
- W4387221640 hasConcept C2780017307 @default.
- W4387221640 hasConcept C2780471494 @default.
- W4387221640 hasConcept C42360764 @default.
- W4387221640 hasConcept C49852136 @default.
- W4387221640 hasConcept C521977710 @default.
- W4387221640 hasConceptScore W4387221640C127413603 @default.
- W4387221640 hasConceptScore W4387221640C159985019 @default.
- W4387221640 hasConceptScore W4387221640C161790260 @default.
- W4387221640 hasConceptScore W4387221640C178790620 @default.
- W4387221640 hasConceptScore W4387221640C185592680 @default.
- W4387221640 hasConceptScore W4387221640C188027245 @default.
- W4387221640 hasConceptScore W4387221640C192562407 @default.
- W4387221640 hasConceptScore W4387221640C2779751980 @default.
- W4387221640 hasConceptScore W4387221640C2780017307 @default.
- W4387221640 hasConceptScore W4387221640C2780471494 @default.
- W4387221640 hasConceptScore W4387221640C42360764 @default.
- W4387221640 hasConceptScore W4387221640C49852136 @default.
- W4387221640 hasConceptScore W4387221640C521977710 @default.
- W4387221640 hasLocation W43872216401 @default.
- W4387221640 hasOpenAccess W4387221640 @default.
- W4387221640 hasPrimaryLocation W43872216401 @default.
- W4387221640 hasRelatedWork W1914086311 @default.
- W4387221640 hasRelatedWork W2053707920 @default.
- W4387221640 hasRelatedWork W2124295290 @default.
- W4387221640 hasRelatedWork W2351111204 @default.