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- W4387233429 abstract "The electron transfer pathway activated by peroxymonosulfate (PMS) has garnered significant attention for the removal of emerging organic pollutants from water. However, overcoming the two-step energy barriers involved in electron transport across reaction interfaces presents a formidable challenge. To surmount the two-step energy barriers of pollutant-catalyst and catalyst-PMS, a catalyst with nano-island structure was developed, forming efficient ternary catalytic interfaces with PMS and pollutants. The presence of atomic pairs within the catalyst punched through the electron transport channels, resulting in a pseudo-first-order kinetic rate of 2.06 min-1 for bisphenol A, which was 5.1 times higher than that of the control sample. The electronic coupling of atomic pairs exerted a profound impact on the splitting of d-orbitals, effectively elevating the d-orbital unoccupancy and reducing the two-step energy barriers encountered by electrons from pollutants to catalysts, and subsequently to PMS, which promoted efficient degradation of pollutants. Furthermore, through the association of two-step energy barrier, the feasibility of utilizing the orbital interaction as a descriptor of the degradation rate by electron-mediated PMS activation was demonstrated. Additionally, the intermediates generated through electron transfer pathway exhibited a lower risk of bioaccumulation. This work inspires insights into the electron-mediated mechanism of multinary catalytic interface reactions." @default.
- W4387233429 created "2023-10-02" @default.
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- W4387233429 date "2024-02-01" @default.
- W4387233429 modified "2023-10-15" @default.
- W4387233429 title "Unveiling enhanced electron-mediated peroxymonosulfate activation for degradation of emerging organic pollutants" @default.
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- W4387233429 doi "https://doi.org/10.1016/j.apcatb.2023.123356" @default.
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