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- W4387241815 abstract "By harnessing the power of coordination self-assembly, crystalline materials can act as carriers for photoacids. Unlike their solution-based counterparts, these photoacids are capable of altering the properties of the crystalline material under light and can even generate proton transfer in a solid-state environment. Due to the photoinduced proton transfer and charge transfer processes within this functional material, this crystal exhibits powerful absorption spanning the visible to near-infrared spectrum upon light irradiation. This feature enables reproducible, significant chromatic variation, near-infrared photothermal conversion, and photocontrollable conductivity for this photoresponsive material. The findings suggest that the synthesis of pyranine photoacid-based crystalline materials via coordination self-assembly can not only enhance light-harvesting efficiency but also enable excited-state proton transfer processes within solid crystalline materials, thereby maintaining and even improving the properties of photoacids." @default.
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- W4387241815 date "2023-10-02" @default.
- W4387241815 modified "2023-10-18" @default.
- W4387241815 title "Excited-State Proton Transfer in a Photoacid-Based Crystalline Coordination Compound: Reversible Photochromism, Near-Infrared Photothermal Conversion, and Conductivity" @default.
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- W4387241815 doi "https://doi.org/10.1021/acs.inorgchem.3c02271" @default.
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