FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387246617> ?p ?o ?g. }

• W4387246617 endingPage "127218" @default.
• W4387246617 startingPage "127218" @default.
• W4387246617 abstract "Stannous octanoate [Sn(Oct)2] and 4-dimethylamino pyridine (DMAP) were used to catalyze the synthesis of amphiphilic cellulose-based graft copolymers, but the acute toxicity of tin ions and DMAP prompts the need for the application of less harmful catalysts. Herein, green catalyst complexes 1–3 [M(H0.5L)2(H2O)5]·2(H2O) (M = Sm, 1; M = Nd, 2; M = Eu, 3; H2L = 4-(3-(tetrazol-5-yl)pyridin-5-yl)benzoic acid) were synthesized, and their properties were systematically investigated. Single-crystal X-ray diffraction showed that the complexes possessed a zero-dimensional structure, while the thermogravimetry and scanning electron microscopy results confirmed their stability after heating at 110 °C for 10 h. Using complexes 1–3 and DMAP as the catalysts, CNFs were grafted with l-lactide via homogeneous ring-opening polymerization to form wood cellulose nanofibers grafted with l-lactide (WGLAs), and the effects of the ratio of wood cellulose nanofibers (WCNFs) to l-lactide ([AGU]/[LA]) and catalyst dosage were studied. The polymerization followed the coordination–insertion mechanism. Under comparable reaction conditions, the grafting ratio of WGLA-1 reached 84.7 %, and the grafting ratio of complex 1 was found to be higher than those achieved using DMAP. WGLAs demonstrated good thermal stability without cytotoxicity, and the residual catalysts in the WGLAs exhibited fluorescence characteristics. Overall, amphiphilic cellulose-based materials with fluorescence emission offered a promising modification strategy to prepare high-performance polymer composites for agriculture and biomedical application." @default.
• W4387246617 created "2023-10-03" @default.
• W4387246617 creator A5023874262 @default.
• W4387246617 creator A5027722684 @default.
• W4387246617 creator A5048352507 @default.
• W4387246617 creator A5059720857 @default.
• W4387246617 creator A5064787244 @default.
• W4387246617 creator A5077149328 @default.
• W4387246617 date "2023-12-01" @default.
• W4387246617 modified "2023-10-17" @default.
• W4387246617 title "Synthesis and catalytic performance of wood cellulose nanofibers grafted with polylactic acid in rare-earth complexes based on tetrazole carboxylic acids" @default.
• W4387246617 cites W1921987889 @default.
• W4387246617 cites W1969360633 @default.
• W4387246617 cites W1972338058 @default.
• W4387246617 cites W1974878172 @default.
• W4387246617 cites W1980965806 @default.
• W4387246617 cites W1983855455 @default.
• W4387246617 cites W1985899670 @default.
• W4387246617 cites W1996123770 @default.
• W4387246617 cites W2003360454 @default.
• W4387246617 cites W2006562372 @default.
• W4387246617 cites W2012216073 @default.
• W4387246617 cites W2032460625 @default.
• W4387246617 cites W2043409626 @default.
• W4387246617 cites W2059205366 @default.
• W4387246617 cites W2083282609 @default.
• W4387246617 cites W2143842899 @default.
• W4387246617 cites W2145587477 @default.
• W4387246617 cites W2160766439 @default.
• W4387246617 cites W2270709893 @default.
• W4387246617 cites W2308069836 @default.
• W4387246617 cites W2316201354 @default.
• W4387246617 cites W2320831021 @default.
• W4387246617 cites W2322524145 @default.
• W4387246617 cites W2343251381 @default.
• W4387246617 cites W2462120834 @default.
• W4387246617 cites W2516611502 @default.
• W4387246617 cites W2520838552 @default.
• W4387246617 cites W2565251939 @default.
• W4387246617 cites W2735900953 @default.
• W4387246617 cites W2903879275 @default.
• W4387246617 cites W2921060216 @default.
• W4387246617 cites W2921194412 @default.
• W4387246617 cites W2945041900 @default.
• W4387246617 cites W2945837214 @default.
• W4387246617 cites W2947247809 @default.
• W4387246617 cites W2970694256 @default.
• W4387246617 cites W2986409997 @default.
• W4387246617 cites W3000808217 @default.
• W4387246617 cites W3086088571 @default.
• W4387246617 cites W3111629525 @default.
• W4387246617 cites W3126686850 @default.
• W4387246617 cites W3143037560 @default.
• W4387246617 cites W3162402876 @default.
• W4387246617 cites W3167778512 @default.
• W4387246617 cites W3171832475 @default.
• W4387246617 cites W3172786962 @default.
• W4387246617 cites W3177581045 @default.
• W4387246617 cites W3191524100 @default.
• W4387246617 cites W3191592486 @default.
• W4387246617 cites W3202178131 @default.
• W4387246617 cites W3216146054 @default.
• W4387246617 cites W3216861170 @default.
• W4387246617 cites W4200594720 @default.
• W4387246617 cites W4205568807 @default.
• W4387246617 cites W4205854381 @default.
• W4387246617 cites W4220744325 @default.
• W4387246617 cites W4220912679 @default.
• W4387246617 cites W4221069074 @default.
• W4387246617 cites W4225155537 @default.
• W4387246617 cites W4229332568 @default.
• W4387246617 cites W4281989361 @default.
• W4387246617 cites W4283078782 @default.
• W4387246617 cites W4285007346 @default.
• W4387246617 cites W4285086897 @default.
• W4387246617 cites W4293506312 @default.
• W4387246617 cites W4306767416 @default.
• W4387246617 cites W4320894715 @default.
• W4387246617 cites W4380577142 @default.
• W4387246617 cites W4383999123 @default.
• W4387246617 doi "https://doi.org/10.1016/j.ijbiomac.2023.127218" @default.
• W4387246617 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37793529" @default.
• W4387246617 hasPublicationYear "2023" @default.
• W4387246617 type Work @default.
• W4387246617 citedByCount "0" @default.
• W4387246617 crossrefType "journal-article" @default.
• W4387246617 hasAuthorship W4387246617A5023874262 @default.
• W4387246617 hasAuthorship W4387246617A5027722684 @default.
• W4387246617 hasAuthorship W4387246617A5048352507 @default.
• W4387246617 hasAuthorship W4387246617A5059720857 @default.
• W4387246617 hasAuthorship W4387246617A5064787244 @default.
• W4387246617 hasAuthorship W4387246617A5077149328 @default.
• W4387246617 hasConcept C13965031 @default.
• W4387246617 hasConcept C161790260 @default.
• W4387246617 hasConcept C171250308 @default.
• W4387246617 hasConcept C178790620 @default.
• W4387246617 hasConcept C185592680 @default.
• W4387246617 hasConcept C188027245 @default.

• next