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- W4387324468 abstract "Ruthenium (III) complexes (1-5) with general composition [Ru(L1-4)3] and [Ru(HL5)3Cl3] where L1 = benzohydroximato (1), L2 = salicylhydroximato (2), L3 = acetohydroximato (3), L4 = hydroxyureato (4), HL 5 = N-hydroxy-N-phenylbenzamide (5) were synthesized by reacting RuCl3.3H2O with respective hydroxamic acids in 1:3 molar ratio . The complexes were characterized using various techniques including ruthenium metal analysis, elemental analysis, UV-Vis, FT-IR, NMR (1H and 13C), and mass spectrometry. Antibacterial activity of the complexes was evaluated using the agar well diffusion method against ten pathogenic strains. The complexes showed significant inhibition zones and were more active than their corresponding ligands. DNA binding studies indicated intercalative binding mode, with hypochromism and red shift observed. Computational and structural parameters were determined using Frontier Molecular Orbital (FMO) energies and Density Functional Theory (DFT) calculations. The complexes demonstrated favorable molecular geometry, chemical reactivity, and biological activity." @default.
- W4387324468 created "2023-10-04" @default.
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- W4387324468 date "2024-01-01" @default.
- W4387324468 modified "2023-10-12" @default.
- W4387324468 title "Antibacterial and ct-DNA binding studies of new synthesized Ruthenium (III) hydroxamate complexes: Design, synthesis, DFT calculations and in-vitro study." @default.
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- W4387324468 doi "https://doi.org/10.1016/j.molstruc.2023.136788" @default.
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