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- W4387332156 abstract "A new organo-samarium complex [Sm(tfac)3(DPEPO)] (Sm1) has been synthesized by incorporating trifluoroacetylacetone (tfac) as the primary antenna ligand and bis(2-(diphenylphosphino)phenyl)ether oxide (DPEPO) as the ancillary ligand. The structure of the complex was established by single crystal X-ray diffraction (SC-XRD) analysis, which shows that the coordination sphere is composed of a EuO6O2 core (octacoordinated). Continuous shape measures (CShMs) further revealed that the geometry around Sm(III) is trigonal dodecahedral with approximate D2d-symmetry. Different non-covalent interactions (NCIs) and their % contribution to the supramolecular structure and their role in stabilizing the structure were determined by Hirshfeld surface analysis. Photophysical properties of the complex were determined in the solid-state and in DCM solution. The complex emits brilliant red emission in the solid-state and in DCM solution with excited state lifetime in microsecond regime and relative quantum yield of 2.5±10 % in solution." @default.
- W4387332156 created "2023-10-05" @default.
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- W4387332156 date "2023-10-01" @default.
- W4387332156 modified "2023-10-14" @default.
- W4387332156 title "Synthesis, X-ray crystal structure and determination of non-covalent interactions through Hirshfeld surface analysis of a pure red emitting asymmetrical octacoordinated Sm(III) complex" @default.
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- W4387332156 doi "https://doi.org/10.1016/j.poly.2023.116673" @default.
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