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- W4387344870 abstract "A highly enantioselective intramolecular NHC-catalyzed approach for the synthesis of fluoroalkylated benzopyranones and 3-coumaranones with all-carbon quaternary stereocenters is presented. This reaction is catalyzed by N-heterocyclic carbenes (NHCs) and involves annulation reactions between in situ generated acyl anion intermediates and highly substituted trifluoromethyl-β,β-disubstituted Michael acceptors. The method can also be extended to perfluoroalkyl homologues." @default.
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- W4387344870 date "2023-10-04" @default.
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- W4387344870 title "Enantioselective Synthesis of Highly Substituted Fluoroalkylated Benzopyranones and 3-Coumaranones via <i>N</i>-Heterocyclic Carbene-Catalyzed Intramolecular Annulations" @default.
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- W4387344870 doi "https://doi.org/10.1021/acs.joc.3c01099" @default.
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