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- W4387355654 abstract "Samples suitable for electron diffraction studies must satisfy certain characteristics such as having a thickness in the range of 10 - 100 nm. We report, to our knowledge, the first successful synthesis technique of nanometer-thin sheets of single-crystalline thymine suitable for electron diffraction and spectroscopy studies. This development provides a well defined system to explore issues related to UV photochemistry of DNA and high intrinsic stability essential to maintaining integrity of genetic information. The crystals are grown using the evaporation technique and the nanometer-thin sheets are obtained via microtoming. The sample is characterized via x-ray diffraction (XRD) and is subsequently studied using electron diffraction via a transmission electron microscope (TEM). The electron damage threshold is determined to be a factor of 10 higher than similar molecular moieties, which further highlights the extremely fast relaxation processes of electron scattering-induced excited states, extending the concept of radiation hardening beyond photoexcited states. The high stability of thymine in particular opens the door for further studies of these ultrafast relaxation processes giving rise to the high stability of DNA to UV radiation." @default.
- W4387355654 created "2023-10-05" @default.
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- W4387355654 date "2023-10-02" @default.
- W4387355654 modified "2023-10-06" @default.
- W4387355654 title "Synthesis technique and electron beam damage study of nanometer-thin single-crystalline Thymine" @default.
- W4387355654 doi "https://doi.org/10.48550/arxiv.2310.01599" @default.
- W4387355654 hasPublicationYear "2023" @default.
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