FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387363406> ?p ?o ?g. }

• W4387363406 endingPage "2947" @default.
• W4387363406 startingPage "2942" @default.
• W4387363406 abstract "CALF-20 is a zinc-triazole-oxalate-based metal–organic framework (MOF) that exhibits selective CO2 physisorption, which makes it attractive for potential applications in CO2 capture. However, to implement such applications, the CALF-20 structure must endure extended exposure to environmental conditions that may lead to changes in structure, chemistry, and, hence, performance. Here we find that the originally reported CALF-20 phase (now denoted α-CALF-20) undergoes a structure transformation following exposure to humid environments to generate a new polymorph, β-CALF-20, identified here through combined synchrotron powder X-ray diffraction and pair distribution function (PDF) analysis. This α-to-β transformation is fully reversible with α-CALF-20 being regenerated by treating β-CALF-20 under dry air or vacuum. The rapid reversion of β- to α-CALF-20 under conditions relevant to measuring the gas adsorption isotherm required the CO2 adsorption properties for β-CALF-20 to be evaluated computationally. Experimental evaluation of the adsorption behavior of β-CALF-20 is not practical. These analyses suggest that β-CALF-20 has a higher CO2 heat of adsorption than α-CALF-20, which may be advantageous to CO2 sorption selectivity at low partial pressures." @default.
• W4387363406 created "2023-10-06" @default.
• W4387363406 creator A5001600445 @default.
• W4387363406 creator A5005468708 @default.
• W4387363406 creator A5012548993 @default.
• W4387363406 creator A5017714289 @default.
• W4387363406 creator A5022805732 @default.
• W4387363406 creator A5045738676 @default.
• W4387363406 creator A5077682713 @default.
• W4387363406 creator A5089971271 @default.
• W4387363406 creator A5091518108 @default.
• W4387363406 date "2023-10-05" @default.
• W4387363406 modified "2023-10-06" @default.
• W4387363406 title "Humidity-Responsive Polymorphism in CALF-20: A Resilient MOF Physisorbent for CO₂ Capture" @default.
• W4387363406 cites W1482891665 @default.
• W4387363406 cites W1914277881 @default.
• W4387363406 cites W1962946586 @default.
• W4387363406 cites W1967485833 @default.
• W4387363406 cites W1981368803 @default.
• W4387363406 cites W1990536516 @default.
• W4387363406 cites W2003949305 @default.
• W4387363406 cites W2019465613 @default.
• W4387363406 cites W2045852818 @default.
• W4387363406 cites W2050863372 @default.
• W4387363406 cites W2067263573 @default.
• W4387363406 cites W2098336232 @default.
• W4387363406 cites W2143363730 @default.
• W4387363406 cites W2189358160 @default.
• W4387363406 cites W2318044185 @default.
• W4387363406 cites W2323403662 @default.
• W4387363406 cites W2402426102 @default.
• W4387363406 cites W2469117827 @default.
• W4387363406 cites W2508859475 @default.
• W4387363406 cites W2511869034 @default.
• W4387363406 cites W2784103179 @default.
• W4387363406 cites W2885571382 @default.
• W4387363406 cites W2991441339 @default.
• W4387363406 cites W3014955140 @default.
• W4387363406 cites W3139856626 @default.
• W4387363406 cites W4200535306 @default.
• W4387363406 cites W4214639826 @default.
• W4387363406 cites W4290667476 @default.
• W4387363406 cites W4376603983 @default.
• W4387363406 cites W4385295480 @default.
• W4387363406 doi "https://doi.org/10.1021/acsmaterialslett.3c00930" @default.
• W4387363406 hasPublicationYear "2023" @default.
• W4387363406 type Work @default.
• W4387363406 citedByCount "0" @default.
• W4387363406 crossrefType "journal-article" @default.
• W4387363406 hasAuthorship W4387363406A5001600445 @default.
• W4387363406 hasAuthorship W4387363406A5005468708 @default.
• W4387363406 hasAuthorship W4387363406A5012548993 @default.
• W4387363406 hasAuthorship W4387363406A5017714289 @default.
• W4387363406 hasAuthorship W4387363406A5022805732 @default.
• W4387363406 hasAuthorship W4387363406A5045738676 @default.
• W4387363406 hasAuthorship W4387363406A5077682713 @default.
• W4387363406 hasAuthorship W4387363406A5089971271 @default.
• W4387363406 hasAuthorship W4387363406A5091518108 @default.
• W4387363406 hasConcept C121332964 @default.
• W4387363406 hasConcept C127413603 @default.
• W4387363406 hasConcept C147789679 @default.
• W4387363406 hasConcept C150394285 @default.
• W4387363406 hasConcept C151420433 @default.
• W4387363406 hasConcept C179104552 @default.
• W4387363406 hasConcept C179366358 @default.
• W4387363406 hasConcept C185544564 @default.
• W4387363406 hasConcept C185592680 @default.
• W4387363406 hasConcept C21368211 @default.
• W4387363406 hasConcept C2776351790 @default.
• W4387363406 hasConcept C2780050857 @default.
• W4387363406 hasConcept C42360764 @default.
• W4387363406 hasConcept C58445606 @default.
• W4387363406 hasConcept C8010536 @default.
• W4387363406 hasConcept C97355855 @default.
• W4387363406 hasConceptScore W4387363406C121332964 @default.
• W4387363406 hasConceptScore W4387363406C127413603 @default.
• W4387363406 hasConceptScore W4387363406C147789679 @default.
• W4387363406 hasConceptScore W4387363406C150394285 @default.
• W4387363406 hasConceptScore W4387363406C151420433 @default.
• W4387363406 hasConceptScore W4387363406C179104552 @default.
• W4387363406 hasConceptScore W4387363406C179366358 @default.
• W4387363406 hasConceptScore W4387363406C185544564 @default.
• W4387363406 hasConceptScore W4387363406C185592680 @default.
• W4387363406 hasConceptScore W4387363406C21368211 @default.
• W4387363406 hasConceptScore W4387363406C2776351790 @default.
• W4387363406 hasConceptScore W4387363406C2780050857 @default.
• W4387363406 hasConceptScore W4387363406C42360764 @default.
• W4387363406 hasConceptScore W4387363406C58445606 @default.
• W4387363406 hasConceptScore W4387363406C8010536 @default.
• W4387363406 hasConceptScore W4387363406C97355855 @default.
• W4387363406 hasFunder F4320337480 @default.
• W4387363406 hasLocation W43873634061 @default.
• W4387363406 hasOpenAccess W4387363406 @default.
• W4387363406 hasPrimaryLocation W43873634061 @default.
• W4387363406 hasRelatedWork W2019408002 @default.
• W4387363406 hasRelatedWork W2022371406 @default.
• W4387363406 hasRelatedWork W2028040544 @default.
• W4387363406 hasRelatedWork W2044792071 @default.

• next