FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387364232> ?p ?o ?g. }

• W4387364232 endingPage "124375" @default.
• W4387364232 startingPage "124375" @default.
• W4387364232 abstract "We discovered that triethanolamine (TEOA) can break Co–N bonds in a 2D Co(II)-imidazole MOF, {[Co(TIB)2(H2O)4]SO4} (TIB stands for 1,3,5-tris(1-imidazolyl) benzene) (CoTIB) to form the ultrafine fragments of CoTIB with sizes less than 5.6 nm under stirring, which are highly efficient and selective (>99%) heterogenous cocatalysts for the visible-light-driven photocatalytic CO2 reduction reaction to CO. The efficiency of the ultrafine fragments of CoTIB (2.0–4.2 nm) reaches 42.7 mmol g−1 h−1 or a TOF of 33.7 h−1 based on Co atoms, which are among the best of heterogenous cocatalyst for photocatalytic CO2RR to CO systems. They are also highly stable under stirring with a TON greater than 909 in 54 h. The ultrafine fragments of CoTIB in mixed solvents were obtained by filtration, using a 0.22 μm filter head, of the 9-h stirred mixture of CoTIB/CH3CN/TEOA/trace-H2O or the 9-h reaction mixture using 1.0 mg of CoTIB. The fragments of CoTIB in these filtrates were characterized by high-resolution mass spectrometry (DI-HRMS), size distribution and Zeta-potential measurements, ICP-MS, as well as Linear-Sweep-Voltammetry (LSV) measurements. The formation process of these nanoparticles and the mechanisms of the photocatalytic CO2RRs were proposed. In addition, this work provides an easy method for making ultrafine fragments (<10 nm) of a Co(II)-imidazole MOF or other MOFs, which could also be viewed as MOF nanoparticles or quantum dots stabilized by coordination of TEOA molecules." @default.
• W4387364232 created "2023-10-06" @default.
• W4387364232 creator A5019365638 @default.
• W4387364232 creator A5062709913 @default.
• W4387364232 creator A5063215288 @default.
• W4387364232 creator A5065061909 @default.
• W4387364232 creator A5088960684 @default.
• W4387364232 date "2023-10-01" @default.
• W4387364232 modified "2023-10-06" @default.
• W4387364232 title "Ultrafine fragments of a 2D Co(II)-Imidazole MOF as cocatalysts for highly efficient and selective visible-light-driven reduction of CO2 to CO" @default.
• W4387364232 cites W1976269136 @default.
• W4387364232 cites W2048088286 @default.
• W4387364232 cites W2051790764 @default.
• W4387364232 cites W2171104153 @default.
• W4387364232 cites W2211270439 @default.
• W4387364232 cites W2605749465 @default.
• W4387364232 cites W2755179486 @default.
• W4387364232 cites W2788750592 @default.
• W4387364232 cites W2804125792 @default.
• W4387364232 cites W2896158573 @default.
• W4387364232 cites W2939393711 @default.
• W4387364232 cites W2943854791 @default.
• W4387364232 cites W2959696670 @default.
• W4387364232 cites W2997646963 @default.
• W4387364232 cites W3011486545 @default.
• W4387364232 cites W3082892192 @default.
• W4387364232 cites W3203653024 @default.
• W4387364232 cites W4200317845 @default.
• W4387364232 cites W4205691648 @default.
• W4387364232 cites W4221020842 @default.
• W4387364232 cites W4223641253 @default.
• W4387364232 cites W4285411691 @default.
• W4387364232 cites W4303022707 @default.
• W4387364232 cites W4309402130 @default.
• W4387364232 cites W4310149530 @default.
• W4387364232 cites W4310156766 @default.
• W4387364232 cites W4311764061 @default.
• W4387364232 cites W4377157172 @default.
• W4387364232 cites W4383959615 @default.
• W4387364232 doi "https://doi.org/10.1016/j.jssc.2023.124375" @default.
• W4387364232 hasPublicationYear "2023" @default.
• W4387364232 type Work @default.
• W4387364232 citedByCount "0" @default.
• W4387364232 crossrefType "journal-article" @default.
• W4387364232 hasAuthorship W4387364232A5019365638 @default.
• W4387364232 hasAuthorship W4387364232A5062709913 @default.
• W4387364232 hasAuthorship W4387364232A5063215288 @default.
• W4387364232 hasAuthorship W4387364232A5065061909 @default.
• W4387364232 hasAuthorship W4387364232A5088960684 @default.
• W4387364232 hasConcept C104663316 @default.
• W4387364232 hasConcept C113196181 @default.
• W4387364232 hasConcept C155672457 @default.
• W4387364232 hasConcept C161790260 @default.
• W4387364232 hasConcept C171250308 @default.
• W4387364232 hasConcept C178790620 @default.
• W4387364232 hasConcept C185592680 @default.
• W4387364232 hasConcept C192562407 @default.
• W4387364232 hasConcept C2775897365 @default.
• W4387364232 hasConcept C2780874372 @default.
• W4387364232 hasConcept C49040817 @default.
• W4387364232 hasConcept C65165184 @default.
• W4387364232 hasConcept C75473681 @default.
• W4387364232 hasConceptScore W4387364232C104663316 @default.
• W4387364232 hasConceptScore W4387364232C113196181 @default.
• W4387364232 hasConceptScore W4387364232C155672457 @default.
• W4387364232 hasConceptScore W4387364232C161790260 @default.
• W4387364232 hasConceptScore W4387364232C171250308 @default.
• W4387364232 hasConceptScore W4387364232C178790620 @default.
• W4387364232 hasConceptScore W4387364232C185592680 @default.
• W4387364232 hasConceptScore W4387364232C192562407 @default.
• W4387364232 hasConceptScore W4387364232C2775897365 @default.
• W4387364232 hasConceptScore W4387364232C2780874372 @default.
• W4387364232 hasConceptScore W4387364232C49040817 @default.
• W4387364232 hasConceptScore W4387364232C65165184 @default.
• W4387364232 hasConceptScore W4387364232C75473681 @default.
• W4387364232 hasLocation W43873642321 @default.
• W4387364232 hasOpenAccess W4387364232 @default.
• W4387364232 hasPrimaryLocation W43873642321 @default.
• W4387364232 hasRelatedWork W1976504271 @default.
• W4387364232 hasRelatedWork W2063384240 @default.
• W4387364232 hasRelatedWork W2080109862 @default.
• W4387364232 hasRelatedWork W2569071712 @default.
• W4387364232 hasRelatedWork W2900557034 @default.
• W4387364232 hasRelatedWork W2971454175 @default.
• W4387364232 hasRelatedWork W3210285899 @default.
• W4387364232 hasRelatedWork W4385433259 @default.
• W4387364232 hasRelatedWork W4387258219 @default.
• W4387364232 hasRelatedWork W3144331481 @default.
• W4387364232 isParatext "false" @default.
• W4387364232 isRetracted "false" @default.
• W4387364232 workType "article" @default.