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• W4387397668 abstract "Extending a selected cyanometalate block into a higher dimensional framework continues to present intriguing challenges in the fields of chemistry and material science. Here, we prepared two rope-like chain compounds of {[(Tp*Me)Fe(CN)3]2Cu2X2(L)}·sol (1, X = Cl, L = (MeCN)0.5(H2O/MeOH)0.5, sol = 2MeCN·1.5H2O; 2, X = Br, L = MeOH, sol = 2MeCN·0.75H2O; Tp*Me = tris(3, 4, 5-trimethylpyrazole)borate) in which the cyanide-bridged trigonal-bipyramidal [Fe2Cu3] subunits were linked with the adjacent ones via two vertex Cu(II) centers, providing a new cyanometallate chain archetype. Direct current magnetic study revealed the presence of ferromagnetic couplings between Fe(III) and Cu(II) ions and uniaxial anisotropy due to a favorable alignment of the anisotropic tricyanoiron(III) units. Moreover, compound 1 exhibits single-chain magnet behavior with an appreciable energy barrier of 72 K, while 2 behaves as a metamagnet, likely caused by the subtle changes in the interchain interactions." @default.
• W4387397668 created "2023-10-07" @default.
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• W4387397668 date "2023-10-06" @default.
• W4387397668 modified "2023-10-17" @default.
• W4387397668 title "Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe₂Cu₃] Subunits" @default.
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• W4387397668 doi "https://doi.org/10.1021/acs.inorgchem.3c02986" @default.
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• W4387397668 hasPublicationYear "2023" @default.
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