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- W4387398482 endingPage "114407" @default.
- W4387398482 startingPage "114407" @default.
- W4387398482 abstract "Albeit the numerous scientific advantages provided by macrocyclic compounds, there is still a significant gap between the “proof of concept” research and their application. This is a direct consequence of the challenging macrocyclization reactions generally involved in their production. Indeed, macrocyclizations are against the principles of Green Chemistry, as long reaction times, high dilution conditions, and solvent-consuming purification techniques are commonly needed. However, new tools -catalysts, templates, preorganization, flow chemistry- are blossoming to develop environmentally friendly approaches for synthesizing macrocycles. Here, we present some of these tools together with a simple metric to assess the environmental impact of several reported macrocyclic systems. The metric has been proved as a useful way to scrutinize macrocyclizations, even in the cases where other environmental metrics such as E-Factor and Emac did not show conclusive results." @default.
- W4387398482 created "2023-10-07" @default.
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- W4387398482 date "2024-01-01" @default.
- W4387398482 modified "2023-10-18" @default.
- W4387398482 title "Tools and new metric (Macrocyclization Environmental Impact - MEI) to tackle the sustainability of macrocyclization reactions" @default.
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- W4387398482 doi "https://doi.org/10.1016/j.cattod.2023.114407" @default.
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