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- W4387399998 endingPage "140381" @default.
- W4387399998 startingPage "140381" @default.
- W4387399998 abstract "The world is drawn to the widespread use, toxicity, and bioaccumulation of the Atrazine (AT) and Auramine O (AO). Pesticides and dyes also have endocrine disruptors, genotoxic and persistent properties. Therefore, the photodegradation of AT and AO in water was investigated. Herein, the structural design of Al-ZnFe2O4 incorporated in rGO nanocomposite has been synthesized via facile precipitation and green synthesis methodology. PXRD and microscopic analysis confirmed the reduced crystallinity nature of Al-ZnFe2O4 due to the incorporation of amorphous rGO. The green Al-ZnFe2O4@rGO nanocomposite (AT: 90%; AO: 95%) showed maximum degradation as compared to native nanoparticles with minimum pollutants concentration of 10 mg catalytic dose at neutral pH in sunlight irradiation due to negative zeta potential (-36.0 mV), higher surface area (163 m2g-1) and tailored band gap (2.1 eV). First-order kinetics followed by initial Langmuir adsorption constituted the degradation process. The presence of different radical quenchers (t-BuOH, p-BZQ, Na2EDTA) concluded that hydroxyl radical plays a significant role in the degradation of toxic AT and AO. Green fabricated Al-ZnFe2O4@rGO also showed excellent efficiency for the degradation of AT and AO pollutant in real wastewater sample. Nanocomposite demonstrated remarkable sustainability and cost-effectiveness by remaining effective for up to nine cycles without experiencing any appreciable activity reduction. Due to its favorable surface features, Al-ZnFe2O4@rGO nanocomposite made via green process is a unique and potential photocatalyst for industrial applications." @default.
- W4387399998 created "2023-10-07" @default.
- W4387399998 creator A5037157489 @default.
- W4387399998 creator A5037718790 @default.
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- W4387399998 date "2023-12-01" @default.
- W4387399998 modified "2023-10-15" @default.
- W4387399998 title "One pot green synthesis of Al doped zinc ferrite nanoparticle decorated with reduced graphene oxide for photocatalytic remediation of organic pollutants: Green synthesis, kinetics, and photoactivity" @default.
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- W4387399998 doi "https://doi.org/10.1016/j.chemosphere.2023.140381" @default.
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