Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387403788> ?p ?o ?g. }
Showing items 1 to 60 of
60
with 100 items per page.
- W4387403788 abstract "The preparation and TMSOTf-mediated catalytic carbocupration-silylation of allylic propiolates has been investigated, expanding on previous syntheses of a variety of β-alkyl- and β-aryl-substituted vinylsilanes from an ethyl propiolate precursor. With few exceptions, the series of synthesized O-allyl (E)-vinylsilanes has been isolated in high yields (61-89%) with exceptional diastereoselectivities (E/Z > 20:1). Additionally, we demonstrated a novel LDA-initiated, TMSCl-mediated Ireland-Claisen rearrangement of a representative allylic ester." @default.
- W4387403788 created "2023-10-07" @default.
- W4387403788 creator A5032040166 @default.
- W4387403788 creator A5084093618 @default.
- W4387403788 creator A5091676757 @default.
- W4387403788 date "2023-10-05" @default.
- W4387403788 modified "2023-10-07" @default.
- W4387403788 title "Preparation and Carbocupration-Silylation of Allyl Propiolates: Vicinal Functionalization to Form Polysubstituted (E)-Vinylic Silanes" @default.
- W4387403788 doi "https://doi.org/10.1055/a-2186-6964" @default.
- W4387403788 hasPublicationYear "2023" @default.
- W4387403788 type Work @default.
- W4387403788 citedByCount "0" @default.
- W4387403788 crossrefType "journal-article" @default.
- W4387403788 hasAuthorship W4387403788A5032040166 @default.
- W4387403788 hasAuthorship W4387403788A5084093618 @default.
- W4387403788 hasAuthorship W4387403788A5091676757 @default.
- W4387403788 hasConcept C115537861 @default.
- W4387403788 hasConcept C120095180 @default.
- W4387403788 hasConcept C121349320 @default.
- W4387403788 hasConcept C147789679 @default.
- W4387403788 hasConcept C155647269 @default.
- W4387403788 hasConcept C161790260 @default.
- W4387403788 hasConcept C178790620 @default.
- W4387403788 hasConcept C185592680 @default.
- W4387403788 hasConcept C2778024649 @default.
- W4387403788 hasConcept C2778183973 @default.
- W4387403788 hasConcept C2780263894 @default.
- W4387403788 hasConcept C2780567667 @default.
- W4387403788 hasConcept C2781076698 @default.
- W4387403788 hasConcept C5304478 @default.
- W4387403788 hasConceptScore W4387403788C115537861 @default.
- W4387403788 hasConceptScore W4387403788C120095180 @default.
- W4387403788 hasConceptScore W4387403788C121349320 @default.
- W4387403788 hasConceptScore W4387403788C147789679 @default.
- W4387403788 hasConceptScore W4387403788C155647269 @default.
- W4387403788 hasConceptScore W4387403788C161790260 @default.
- W4387403788 hasConceptScore W4387403788C178790620 @default.
- W4387403788 hasConceptScore W4387403788C185592680 @default.
- W4387403788 hasConceptScore W4387403788C2778024649 @default.
- W4387403788 hasConceptScore W4387403788C2778183973 @default.
- W4387403788 hasConceptScore W4387403788C2780263894 @default.
- W4387403788 hasConceptScore W4387403788C2780567667 @default.
- W4387403788 hasConceptScore W4387403788C2781076698 @default.
- W4387403788 hasConceptScore W4387403788C5304478 @default.
- W4387403788 hasLocation W43874037881 @default.
- W4387403788 hasOpenAccess W4387403788 @default.
- W4387403788 hasPrimaryLocation W43874037881 @default.
- W4387403788 hasRelatedWork W1985489999 @default.
- W4387403788 hasRelatedWork W1989717175 @default.
- W4387403788 hasRelatedWork W2039151994 @default.
- W4387403788 hasRelatedWork W2085366314 @default.
- W4387403788 hasRelatedWork W2170295213 @default.
- W4387403788 hasRelatedWork W2950385267 @default.
- W4387403788 hasRelatedWork W2951801876 @default.
- W4387403788 hasRelatedWork W4234432710 @default.
- W4387403788 hasRelatedWork W4244831109 @default.
- W4387403788 hasRelatedWork W2094363479 @default.
- W4387403788 isParatext "false" @default.
- W4387403788 isRetracted "false" @default.
- W4387403788 workType "article" @default.