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- W4387403795 abstract "In modern advances, BCF catalysts have risen to prominence owing to render versatility for myriad organic reactions. Herein, we introduced an efficient and highly stereoselective α-C-glycosylation strategy by employing a catalytic amount of B(C6F5)3 under mild reaction conditions en route to 2,3-unsaturated C-glycosides. The reaction features a broad functional group tolerance including a variety of glycals coupled with allyltrimethylsilane, and trimethylsilyl phenylacetylene to access the corresponding 2,3-unsaturated allyl- and alkynyl- C-glycosides in excellent α-selectivity. The reaction proceeds in good to excellent yields via concomitant borane activation of glycal donor under mild conditions." @default.
- W4387403795 created "2023-10-07" @default.
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- W4387403795 date "2023-10-05" @default.
- W4387403795 modified "2023-10-07" @default.
- W4387403795 title "Tris(pentafluorophenyl)borane-Catalysed Stereoselective C-Glycosylation of Glycals: A Facile Synthesis of Allyl and Alkynyl glycosides" @default.
- W4387403795 doi "https://doi.org/10.1055/a-2186-7116" @default.
- W4387403795 hasPublicationYear "2023" @default.
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