Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387408087> ?p ?o ?g. }
- W4387408087 endingPage "13527" @default.
- W4387408087 startingPage "13516" @default.
- W4387408087 abstract "Eight-electron nitrate reduction (NO3RR) offers a cost-effective and environmentally friendly route of ammonia production and wastewater remediation. However, identification and reinforcement of the metal–ligand interaction responsible for the catalytic activity in transition-metal phthalocyanine-based heterostructures still remain unclear due to their complexity. Herein, directed by computation, we present a heterostructure approach to couple 2D graphene sheets with 1D manganese (II) phthalocyanine to produce a pyrrolic-N coordinated electron-deficient Mn center that interacts to generate the vital intermediates of the NO3RR process. The catalyst system delivers an ammonia yield rate of 20,316 μg h–1 mgcat–1, a faradaic efficiency (FE) of 98.3%, and an electrocatalytic stability of 50 h. Mechanistic investigations verified by FTIR spectroscopy and theoretical calculations to identify Mn coordinated pyrrolic-N as the active sites in MnPc and RGO reinforce the active sites by orbital interaction for enhancing the charge transfer in the formation of *NOH @ NO3RR intermediates while suppressing the competitive hydrogen evolution reaction (HER), resulting in high selectivity and FE." @default.
- W4387408087 created "2023-10-07" @default.
- W4387408087 creator A5001333189 @default.
- W4387408087 creator A5007239473 @default.
- W4387408087 creator A5012901220 @default.
- W4387408087 creator A5028088995 @default.
- W4387408087 creator A5074149502 @default.
- W4387408087 creator A5082102409 @default.
- W4387408087 creator A5085420740 @default.
- W4387408087 creator A5091324500 @default.
- W4387408087 date "2023-10-06" @default.
- W4387408087 modified "2023-10-17" @default.
- W4387408087 title "Controlling the Metal–Ligand Coordination Environment of Manganese Phthalocyanine in 1D–2D Heterostructure for Enhancing Nitrate Reduction to Ammonia" @default.
- W4387408087 cites W1982154699 @default.
- W4387408087 cites W1987490818 @default.
- W4387408087 cites W1996218409 @default.
- W4387408087 cites W2034589370 @default.
- W4387408087 cites W2063173953 @default.
- W4387408087 cites W2086507590 @default.
- W4387408087 cites W2090940236 @default.
- W4387408087 cites W2111661209 @default.
- W4387408087 cites W2151201269 @default.
- W4387408087 cites W2289106567 @default.
- W4387408087 cites W2292982889 @default.
- W4387408087 cites W2311133126 @default.
- W4387408087 cites W2564515886 @default.
- W4387408087 cites W2803724286 @default.
- W4387408087 cites W2851584547 @default.
- W4387408087 cites W2889634968 @default.
- W4387408087 cites W2920912088 @default.
- W4387408087 cites W2979656578 @default.
- W4387408087 cites W3018229495 @default.
- W4387408087 cites W3018360935 @default.
- W4387408087 cites W3024210043 @default.
- W4387408087 cites W3037254992 @default.
- W4387408087 cites W3044598303 @default.
- W4387408087 cites W3101519145 @default.
- W4387408087 cites W3154334064 @default.
- W4387408087 cites W3160702750 @default.
- W4387408087 cites W3167923530 @default.
- W4387408087 cites W3170771643 @default.
- W4387408087 cites W3174090052 @default.
- W4387408087 cites W3185537446 @default.
- W4387408087 cites W3209612204 @default.
- W4387408087 cites W4214704737 @default.
- W4387408087 cites W4221074508 @default.
- W4387408087 cites W4229006274 @default.
- W4387408087 cites W4280649146 @default.
- W4387408087 cites W4285795914 @default.
- W4387408087 cites W4289922504 @default.
- W4387408087 cites W4292366100 @default.
- W4387408087 cites W4297087658 @default.
- W4387408087 cites W4307906707 @default.
- W4387408087 cites W4309506019 @default.
- W4387408087 cites W4313424879 @default.
- W4387408087 cites W4318619691 @default.
- W4387408087 cites W4319063375 @default.
- W4387408087 cites W4319294785 @default.
- W4387408087 cites W4319835168 @default.
- W4387408087 cites W4328101190 @default.
- W4387408087 cites W4361244192 @default.
- W4387408087 cites W4361990062 @default.
- W4387408087 cites W4363652070 @default.
- W4387408087 cites W4365512316 @default.
- W4387408087 cites W4366506684 @default.
- W4387408087 cites W4375939486 @default.
- W4387408087 cites W4377000781 @default.
- W4387408087 cites W4377247927 @default.
- W4387408087 cites W4381435320 @default.
- W4387408087 cites W4384300705 @default.
- W4387408087 doi "https://doi.org/10.1021/acscatal.3c02747" @default.
- W4387408087 hasPublicationYear "2023" @default.
- W4387408087 type Work @default.
- W4387408087 citedByCount "0" @default.
- W4387408087 crossrefType "journal-article" @default.
- W4387408087 hasAuthorship W4387408087A5001333189 @default.
- W4387408087 hasAuthorship W4387408087A5007239473 @default.
- W4387408087 hasAuthorship W4387408087A5012901220 @default.
- W4387408087 hasAuthorship W4387408087A5028088995 @default.
- W4387408087 hasAuthorship W4387408087A5074149502 @default.
- W4387408087 hasAuthorship W4387408087A5082102409 @default.
- W4387408087 hasAuthorship W4387408087A5085420740 @default.
- W4387408087 hasAuthorship W4387408087A5091324500 @default.
- W4387408087 hasConcept C106773901 @default.
- W4387408087 hasConcept C116569031 @default.
- W4387408087 hasConcept C161790260 @default.
- W4387408087 hasConcept C170493617 @default.
- W4387408087 hasConcept C171250308 @default.
- W4387408087 hasConcept C178790620 @default.
- W4387408087 hasConcept C179104552 @default.
- W4387408087 hasConcept C185592680 @default.
- W4387408087 hasConcept C192562407 @default.
- W4387408087 hasConcept C2776382133 @default.
- W4387408087 hasConcept C2780761128 @default.
- W4387408087 hasConcept C30080830 @default.
- W4387408087 hasConcept C49040817 @default.
- W4387408087 hasConcept C528890316 @default.
- W4387408087 hasConcept C55493867 @default.