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- W4387417839 abstract "The electrochemically deposited Palladium hexacyanoferrate thin film on Glassy Carbon electrode (PdHCF|GC) has been studied in HCl, KCl and NaCl solutions by in_situ external reflection FTIR spectroelectrochemical technique. It is found that the behavior of the electroactive PdHCF film can be understood in terms of two states: Pd2Fe(II)(CN)6 formed in the inner layer and (M+)2Fe(II)(CN)6 (M+: electrolyte cation) formed in the outer layer. The inner layer is oxidized at Em=0.87 V in 1 mol/L KCl, while for the outer layer Em=0.77 V(vs. Ag/AgCl). In 1 mol/L NaCl or HCl solutions, half_wave potentials of these two layers are not well resolved, however corresponding CN stretching frequencies for the two states have been well observed in all three solutions. H+ has been found as a good supporting electrolyte for redox reactions of these two layers." @default.
- W4387417839 created "2023-10-07" @default.
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- W4387417839 date "1999-05-28" @default.
- W4387417839 modified "2023-10-08" @default.
- W4387417839 title "In Situ FTIR Spectroelectrochemical Study of Palladium Hexacyanoferrate Thin Film Deposited on Glassy Carbon Electrode" @default.
- W4387417839 doi "https://doi.org/10.61558/2993-074x.3177" @default.
- W4387417839 hasPublicationYear "1999" @default.
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