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• W4387424811 abstract "Vapor pressure (psat) data are needed to assess the potential use of terpenes as breath markers of recent cannabis use. Herein, a recently introduced gas-saturation method for psat measurements, known as dynamic vapor microextraction (DVME), was used to measure psat for the terpene (±)-3,7-dimethylocta-1,6-dien-3-ol, commonly known as linalool. The DVME apparatus utilizes inexpensive and commercially available components, a low internal volume, and helium carrier gas to minimize nonideal mixture behavior. In the temperature range from 314 to 354 K, DVME-based measurements of the psat of linalool ranged from 81 to 1250 Pa. With a measurement period of 30 min, the combined standard uncertainty of these measurements ranged from 0.0358·psat to 0.0584·psat depending on temperature. The DVME-based measurements agree with a Wagner correlation of the available literature data. We demonstrate that DVME produces accurate results for values of psat that are 200 times higher than in the DVME validation study with n-eicosane (C20H42). The oxidative stability of linalool was improved by the addition of 0.2 mass % of the antioxidant tert-butylhydroquinone." @default.
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• W4387424811 date "2023-10-07" @default.
• W4387424811 modified "2023-10-18" @default.
• W4387424811 title "Vapor Pressure Measurements on Linalool Using a Rapid and Inexpensive Method Suitable for Cannabis-Associated Terpenes" @default.
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• W4387424811 doi "https://doi.org/10.1021/acs.jced.3c00360" @default.
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