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• W4387426311 endingPage "124380" @default.
• W4387426311 startingPage "124380" @default.
• W4387426311 abstract "We have investigated the crystal structure and electrical properties of Bi3GaSb2O11 at high temperatures. Neither phase transitions nor change in oxygen content were observed at 26–800 °C in air. The crystal structure was successfully refined using neutron diffraction data taken at 26–600 °C. The average thermal expansion coefficient between 26 and 600 °C was 10.4614(7) × 10‒6 °C‒1. There are three different (Ga/Sb)–O bonds of (Ga/Sb)–O3b, (Ga/Sb)–O2, and (Ga/Sb)–O3a. It was found that the thermal expansion coefficient of the (Ga/Sb)–O3a bond is lower than those of other bonds. At 916 °C the total DC electrical conductivity in N2 (1.4 × 10‒3 S cm‒1) was higher than that in air (7.1 × 10‒4 S cm‒1), due to electron conduction in N2. In air, oxide-ion conduction was suggested by electrical conductivity and polarization measurements. Bond-valence-based-energy calculations suggested oxide-ion migration along the O–O edges and on O–O–O faces of (Ga/Sb)O6 octahedra." @default.
• W4387426311 created "2023-10-08" @default.
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• W4387426311 date "2023-10-01" @default.
• W4387426311 modified "2023-10-16" @default.
• W4387426311 title "Structural and electrical properties of Bi3GaSb2O11 at high temperatures" @default.
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• W4387426311 doi "https://doi.org/10.1016/j.jssc.2023.124380" @default.
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