Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387440891> ?p ?o ?g. }
- W4387440891 abstract "Synthesis of unsymmetrical but-2-yne-1,4-diones is reported through oxidative alkyne translocation of readily accessible homopropargylic alcohols. The developed method consists of an unprecedented one-pot sequential electro-oxidative annulation-fragmentation-chemical selenoxide elimination process. Excellent functional group compatibility was observed, and an array of yne-1,4-diones were synthesized. Derivatization of the alkyne gave access to other valuable scaffolds. Detailed mechanistic studies through the isolation of key intermediates clarified the cascade transformation." @default.
- W4387440891 created "2023-10-10" @default.
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- W4387440891 date "2023-10-09" @default.
- W4387440891 modified "2023-10-10" @default.
- W4387440891 title "Electro-oxidative Synthesis of Unsymmetrical Alkyne-1,4-diones via Sequential Ring Formation and Cleavage" @default.
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- W4387440891 doi "https://doi.org/10.1021/acs.orglett.3c03045" @default.
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