Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387451807> ?p ?o ?g. }
- W4387451807 abstract "Abstract An achiral chromophore can acquire a chiral spectroscopic signature when interacting with a chiral environment. This so-called induced chirality is documented in electronic or vibrational circular dichroism, which arises from the coupling between electric and magnetic transition dipoles. Here, we demonstrate that a chiroptical response is also induced within the electric dipole approximation by observing the asymmetric scattering of a photoelectron ejected from an achiral chromophore in interaction with a chiral host. In a phenol–methyloxirane complex, removing an electron from an achiral aromatic π orbital localised on the phenol moiety results in an intense and opposite photoelectron circular dichroism (PECD) for the two enantiomeric complexes with (R) and (S) methyloxirane, evidencing the long-range effect (~5 Å) of the scattering chiral potential. This induced chirality has important structural and analytical implications, discussed here in the context of growing interest in laser-based PECD, for in situ, real time enantiomer determination." @default.
- W4387451807 created "2023-10-10" @default.
- W4387451807 creator A5000130318 @default.
- W4387451807 creator A5004691111 @default.
- W4387451807 creator A5016663373 @default.
- W4387451807 creator A5043028666 @default.
- W4387451807 creator A5046085782 @default.
- W4387451807 creator A5062054896 @default.
- W4387451807 creator A5087647287 @default.
- W4387451807 creator A5093027625 @default.
- W4387451807 date "2023-10-09" @default.
- W4387451807 modified "2023-10-12" @default.
- W4387451807 title "Induced photoelectron circular dichroism onto an achiral chromophore" @default.
- W4387451807 cites W1965410225 @default.
- W4387451807 cites W1972449167 @default.
- W4387451807 cites W1976817234 @default.
- W4387451807 cites W1991454272 @default.
- W4387451807 cites W1993664210 @default.
- W4387451807 cites W1999528683 @default.
- W4387451807 cites W2018271364 @default.
- W4387451807 cites W2022211018 @default.
- W4387451807 cites W2022589105 @default.
- W4387451807 cites W2026400104 @default.
- W4387451807 cites W2029667189 @default.
- W4387451807 cites W2031507115 @default.
- W4387451807 cites W2033999476 @default.
- W4387451807 cites W2035181522 @default.
- W4387451807 cites W2046692048 @default.
- W4387451807 cites W2046833357 @default.
- W4387451807 cites W2049996223 @default.
- W4387451807 cites W2050827839 @default.
- W4387451807 cites W2054119218 @default.
- W4387451807 cites W2054774428 @default.
- W4387451807 cites W2064746197 @default.
- W4387451807 cites W2067339297 @default.
- W4387451807 cites W2067435087 @default.
- W4387451807 cites W2071342308 @default.
- W4387451807 cites W2072859398 @default.
- W4387451807 cites W2074927834 @default.
- W4387451807 cites W2075242477 @default.
- W4387451807 cites W2079046978 @default.
- W4387451807 cites W2079202877 @default.
- W4387451807 cites W2086463183 @default.
- W4387451807 cites W2092157292 @default.
- W4387451807 cites W2096747776 @default.
- W4387451807 cites W2129876339 @default.
- W4387451807 cites W2158314083 @default.
- W4387451807 cites W2160683496 @default.
- W4387451807 cites W2161963899 @default.
- W4387451807 cites W2171839036 @default.
- W4387451807 cites W2222589778 @default.
- W4387451807 cites W2269443440 @default.
- W4387451807 cites W2332371754 @default.
- W4387451807 cites W2335668218 @default.
- W4387451807 cites W2496441917 @default.
- W4387451807 cites W2732238958 @default.
- W4387451807 cites W2763807229 @default.
- W4387451807 cites W2765248401 @default.
- W4387451807 cites W2783331850 @default.
- W4387451807 cites W2800544014 @default.
- W4387451807 cites W2836170657 @default.
- W4387451807 cites W2888147480 @default.
- W4387451807 cites W2902213658 @default.
- W4387451807 cites W3043657725 @default.
- W4387451807 cites W3081542588 @default.
- W4387451807 cites W3085788606 @default.
- W4387451807 cites W3133835454 @default.
- W4387451807 cites W3165019590 @default.
- W4387451807 cites W3166498735 @default.
- W4387451807 cites W3168402428 @default.
- W4387451807 cites W3184677426 @default.
- W4387451807 cites W4206657216 @default.
- W4387451807 cites W4220789778 @default.
- W4387451807 cites W4285493696 @default.
- W4387451807 cites W4302362290 @default.
- W4387451807 cites W4310136372 @default.
- W4387451807 cites W4319460437 @default.
- W4387451807 cites W4377242092 @default.
- W4387451807 doi "https://doi.org/10.1038/s41467-023-42002-1" @default.
- W4387451807 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37813848" @default.
- W4387451807 hasPublicationYear "2023" @default.
- W4387451807 type Work @default.
- W4387451807 citedByCount "0" @default.
- W4387451807 crossrefType "journal-article" @default.
- W4387451807 hasAuthorship W4387451807A5000130318 @default.
- W4387451807 hasAuthorship W4387451807A5004691111 @default.
- W4387451807 hasAuthorship W4387451807A5016663373 @default.
- W4387451807 hasAuthorship W4387451807A5043028666 @default.
- W4387451807 hasAuthorship W4387451807A5046085782 @default.
- W4387451807 hasAuthorship W4387451807A5062054896 @default.
- W4387451807 hasAuthorship W4387451807A5087647287 @default.
- W4387451807 hasAuthorship W4387451807A5093027625 @default.
- W4387451807 hasBestOaLocation W43874518071 @default.
- W4387451807 hasConcept C121332964 @default.
- W4387451807 hasConcept C124668440 @default.
- W4387451807 hasConcept C133571119 @default.
- W4387451807 hasConcept C151730666 @default.
- W4387451807 hasConcept C173523689 @default.
- W4387451807 hasConcept C178790620 @default.
- W4387451807 hasConcept C185592680 @default.