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- W4387472642 abstract "Efficient hydrogenations of terminal alkenes with molecular hydrogen catalyzed by well-defined bench stable Mn(I) complexes containing an N-heterocyclic carbene-based PCP pincer ligand are described. These reactions are environmentally benign and atom economic, implementing an inexpensive, earth abundant non-precious metal catalyst. A range of aromatic and aliphatic alkenes were efficiently converted into alkanes in good to excellent yields. The hydrogenation proceeds at 100 oC with catalyst loadings of 0.25-0.5 mol %, 2.5 - 5 mol % base (KOtBu) and a hydrogen pressure of 20 bar. Mechanistic insight into the catalytic reaction is provided by means of DFT calculations." @default.
- W4387472642 created "2023-10-11" @default.
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- W4387472642 date "2023-10-10" @default.
- W4387472642 modified "2023-10-16" @default.
- W4387472642 title "Hydrogenation of Terminal Alkenes Catalyzed by Air‐Stable Mn(I) Complexes Bearing an N‐Heterocyclic Carbene‐Based PCP Pincer Ligand" @default.
- W4387472642 doi "https://doi.org/10.1002/chem.202302455" @default.
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- W4387472642 hasPublicationYear "2023" @default.
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