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- W4387472806 abstract "An asymmetric [3+2] cycloaddition of quinone esters with 2,3-dihydrofuran has been realized via a newly developed Cu(II)/SPDO complex. It provides straightforward access to 2,3,3a,8a-tetrahydrofuro[2,3-b]benzofurans (TFB) with high enantioselectivity (up to 97.5:2.5 er) and diastereoselectivity (all >20:1 dr). The resulting adducts contain two adjacent stereocenters and a continuously functionalized benzene ring. Additionally, this transformation could be easily performed on a gram scale, allowing for expedient synthesis of natural dihydroaflatoxin D2 and aflatoxin B2." @default.
- W4387472806 created "2023-10-11" @default.
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- W4387472806 date "2023-10-10" @default.
- W4387472806 modified "2023-10-16" @default.
- W4387472806 title "Enantioselective Synthesis of 2,3,3a,8a-Tetrahydrofuro[2,3-<i>b</i>]benzofuran Scaffolds Enabled by Cu(II)/SPDO-Catalyzed [3+2] Cycloaddition of 2,3-Dihydrofuran and Quinone Esters" @default.
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- W4387472806 doi "https://doi.org/10.1021/acs.joc.3c01681" @default.
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- W4387472806 hasPublicationYear "2023" @default.
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