FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387473080> ?p ?o ?g. }

• W4387473080 abstract "Sodium-air batteries (SABs) are receiving considerable attention for the development of next generation battery alternatives due to their high theoretical energy density (up to 1105 W h kg-1). However, most of the studies on this technology are still based on organic solvents; in particular, diglyme, which is highly flammable and toxic for the unborn child. To overcome these safety issues, this research investigates the first use of a branched ether solvent 1,2,3-trimethoxypropane (TMP) as an alternative electrolyte to diglyme for SABs. Through this work, the reactivity of the central tertiary carbon in TMP towards bare sodium metal was identified, while the addition of N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyr][TFSI]) as a co-solvent proved to be an effective strategy to limit the reactivity. Moreover, a Na-β-alumina disk was employed for anode protection, to separate the TMP-based electrolyte from the sodium metal. The new cell design resulted in improved cell performance: discharge capacities of up to 1.92 and 2.31 mA h cm-2 were achieved for the 16.6 mol% NaTFSI in TMP and 16.6 mol% NaTFSI in TMP/[C4mpyr][TFSI] compositions, respectively. By means of SEM, Raman and 23Na NMR techniques, NaO2 cubes were identified to be the major discharge product for both electrolyte compositions. Moreover, the hybrid electrolyte was shown to hinder the formation of side-products during discharge - the ratio of NaO2 to side-products in the hybrid electrolyte was 2.4 compared with 0.8 for the TMP-based electrolyte - and a different charge mechanism for the dissolution of NaO2 cubes for each electrolyte was observed. The findings of this work demonstrate the high potential of TMP as a base solvent for SABs, and the importance of careful electrolyte composition design in order to step towards greener and less toxic batteries." @default.
• W4387473080 created "2023-10-11" @default.
• W4387473080 creator A5003593717 @default.
• W4387473080 creator A5012911399 @default.
• W4387473080 creator A5014518728 @default.
• W4387473080 creator A5017260988 @default.
• W4387473080 creator A5031786919 @default.
• W4387473080 creator A5036598552 @default.
• W4387473080 creator A5070334467 @default.
• W4387473080 creator A5071518935 @default.
• W4387473080 creator A5085717372 @default.
• W4387473080 date "2023-01-01" @default.
• W4387473080 modified "2023-10-16" @default.
• W4387473080 title "Bio-based Ether Solvent and Ionic Liquid Electrolyte for Sustainable Sodium-Air Batteries" @default.
• W4387473080 cites W1976532904 @default.
• W4387473080 cites W2017646729 @default.
• W4387473080 cites W2027144283 @default.
• W4387473080 cites W2064471744 @default.
• W4387473080 cites W2074278890 @default.
• W4387473080 cites W2078866873 @default.
• W4387473080 cites W2087501971 @default.
• W4387473080 cites W2088807292 @default.
• W4387473080 cites W2093899970 @default.
• W4387473080 cites W2124135807 @default.
• W4387473080 cites W2154035368 @default.
• W4387473080 cites W2302328755 @default.
• W4387473080 cites W2343033016 @default.
• W4387473080 cites W2413033680 @default.
• W4387473080 cites W2416447741 @default.
• W4387473080 cites W2418348085 @default.
• W4387473080 cites W2418923412 @default.
• W4387473080 cites W2514282141 @default.
• W4387473080 cites W2524301326 @default.
• W4387473080 cites W2557123524 @default.
• W4387473080 cites W2567151047 @default.
• W4387473080 cites W2571825211 @default.
• W4387473080 cites W2613543643 @default.
• W4387473080 cites W2696343551 @default.
• W4387473080 cites W2734763193 @default.
• W4387473080 cites W2783583916 @default.
• W4387473080 cites W2787667840 @default.
• W4387473080 cites W2790153550 @default.
• W4387473080 cites W2792647912 @default.
• W4387473080 cites W2792791814 @default.
• W4387473080 cites W2797923790 @default.
• W4387473080 cites W2803521326 @default.
• W4387473080 cites W2807436121 @default.
• W4387473080 cites W2810982816 @default.
• W4387473080 cites W2884599302 @default.
• W4387473080 cites W2889780652 @default.
• W4387473080 cites W2913250730 @default.
• W4387473080 cites W2950577826 @default.
• W4387473080 cites W2950745222 @default.
• W4387473080 cites W2953364069 @default.
• W4387473080 cites W2957805515 @default.
• W4387473080 cites W2981870566 @default.
• W4387473080 cites W2982215019 @default.
• W4387473080 cites W2991125037 @default.
• W4387473080 cites W2998083987 @default.
• W4387473080 cites W3006857395 @default.
• W4387473080 cites W3007103777 @default.
• W4387473080 cites W3021802054 @default.
• W4387473080 cites W3023511678 @default.
• W4387473080 cites W3093913102 @default.
• W4387473080 cites W3110645616 @default.
• W4387473080 cites W3124486137 @default.
• W4387473080 cites W3128230384 @default.
• W4387473080 cites W3128340423 @default.
• W4387473080 cites W3129685409 @default.
• W4387473080 cites W3199039666 @default.
• W4387473080 cites W4206558789 @default.
• W4387473080 cites W4224223201 @default.
• W4387473080 cites W4285744170 @default.
• W4387473080 doi "https://doi.org/10.1039/d3fd00096f" @default.
• W4387473080 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37814915" @default.
• W4387473080 hasPublicationYear "2023" @default.
• W4387473080 type Work @default.
• W4387473080 citedByCount "0" @default.
• W4387473080 crossrefType "journal-article" @default.
• W4387473080 hasAuthorship W4387473080A5003593717 @default.
• W4387473080 hasAuthorship W4387473080A5012911399 @default.
• W4387473080 hasAuthorship W4387473080A5014518728 @default.
• W4387473080 hasAuthorship W4387473080A5017260988 @default.
• W4387473080 hasAuthorship W4387473080A5031786919 @default.
• W4387473080 hasAuthorship W4387473080A5036598552 @default.
• W4387473080 hasAuthorship W4387473080A5070334467 @default.
• W4387473080 hasAuthorship W4387473080A5071518935 @default.
• W4387473080 hasAuthorship W4387473080A5085717372 @default.
• W4387473080 hasConcept C121332964 @default.
• W4387473080 hasConcept C127413603 @default.
• W4387473080 hasConcept C147789679 @default.
• W4387473080 hasConcept C154881586 @default.
• W4387473080 hasConcept C161790260 @default.
• W4387473080 hasConcept C163258240 @default.
• W4387473080 hasConcept C17525397 @default.
• W4387473080 hasConcept C178790620 @default.
• W4387473080 hasConcept C179104552 @default.
• W4387473080 hasConcept C185592680 @default.
• W4387473080 hasConcept C2777873371 @default.
• W4387473080 hasConcept C2780407432 @default.

• next