Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387473378> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W4387473378 abstract "The emergence of polymers with intrinsic microporosity provides solutions for flexible gas separation membranes with both high gas permeability and selectivity. However, their applications are significantly hindered by the costly synthetic efforts, limited availability of chemical systems, and narrow window of microporosity sizes. Herein, flexible mixed matrix membranes with tunable intrinsic microporosity can be facilely fabricated from the coordination assembly of polymer brushes and coordination nanocages. Polymer brushes bearing isophthalic acid side groups can coordinate with Cu2+ to assemble into polymer networks crosslinked by 2 nm nanocages. The semi-flexible feature of the polymer brush and the high crosslinking density of the network prevent the network from collapsing during solvent removal and the obtained aerogels demonstrate hierarchical structure with dual porosity from the crosslinked polymer network and coordination nanocage, respectively. The porosity can be facilely tuned via the amount of Cu2+ by regulating the network crosslinking density and nanocage loadings, and finally, optimized gas separation that surpasses Robeson upper bound for H2 /CO2 can be achieved. The coordination-driven assembly protocol paves a new avenue for the cost-effective synthesis of polymers with intrinsic microporosity and the fabrication of flexible gas separation membranes. This article is protected by copyright. All rights reserved." @default.
- W4387473378 created "2023-10-11" @default.
- W4387473378 creator A5036493982 @default.
- W4387473378 creator A5044464889 @default.
- W4387473378 creator A5048476271 @default.
- W4387473378 creator A5082391052 @default.
- W4387473378 creator A5086689871 @default.
- W4387473378 date "2023-10-10" @default.
- W4387473378 modified "2023-10-16" @default.
- W4387473378 title "The Coordination Nanocages‐Integrated Polymer Brush Networks for Flexible Microporous Membranes with Exceptional H<sub>2</sub>/CO<sub>2</sub> Separation Performance" @default.
- W4387473378 doi "https://doi.org/10.1002/marc.202300477" @default.
- W4387473378 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37814593" @default.
- W4387473378 hasPublicationYear "2023" @default.
- W4387473378 type Work @default.
- W4387473378 citedByCount "0" @default.
- W4387473378 crossrefType "journal-article" @default.
- W4387473378 hasAuthorship W4387473378A5036493982 @default.
- W4387473378 hasAuthorship W4387473378A5044464889 @default.
- W4387473378 hasAuthorship W4387473378A5048476271 @default.
- W4387473378 hasAuthorship W4387473378A5082391052 @default.
- W4387473378 hasAuthorship W4387473378A5086689871 @default.
- W4387473378 hasConcept C127413603 @default.
- W4387473378 hasConcept C128355301 @default.
- W4387473378 hasConcept C150394285 @default.
- W4387473378 hasConcept C159985019 @default.
- W4387473378 hasConcept C161790260 @default.
- W4387473378 hasConcept C171250308 @default.
- W4387473378 hasConcept C178790620 @default.
- W4387473378 hasConcept C179366358 @default.
- W4387473378 hasConcept C18411161 @default.
- W4387473378 hasConcept C185592680 @default.
- W4387473378 hasConcept C188027245 @default.
- W4387473378 hasConcept C190399342 @default.
- W4387473378 hasConcept C192562407 @default.
- W4387473378 hasConcept C41625074 @default.
- W4387473378 hasConcept C42360764 @default.
- W4387473378 hasConcept C521977710 @default.
- W4387473378 hasConcept C55493867 @default.
- W4387473378 hasConcept C6648577 @default.
- W4387473378 hasConcept C86381522 @default.
- W4387473378 hasConceptScore W4387473378C127413603 @default.
- W4387473378 hasConceptScore W4387473378C128355301 @default.
- W4387473378 hasConceptScore W4387473378C150394285 @default.
- W4387473378 hasConceptScore W4387473378C159985019 @default.
- W4387473378 hasConceptScore W4387473378C161790260 @default.
- W4387473378 hasConceptScore W4387473378C171250308 @default.
- W4387473378 hasConceptScore W4387473378C178790620 @default.
- W4387473378 hasConceptScore W4387473378C179366358 @default.
- W4387473378 hasConceptScore W4387473378C18411161 @default.
- W4387473378 hasConceptScore W4387473378C185592680 @default.
- W4387473378 hasConceptScore W4387473378C188027245 @default.
- W4387473378 hasConceptScore W4387473378C190399342 @default.
- W4387473378 hasConceptScore W4387473378C192562407 @default.
- W4387473378 hasConceptScore W4387473378C41625074 @default.
- W4387473378 hasConceptScore W4387473378C42360764 @default.
- W4387473378 hasConceptScore W4387473378C521977710 @default.
- W4387473378 hasConceptScore W4387473378C55493867 @default.
- W4387473378 hasConceptScore W4387473378C6648577 @default.
- W4387473378 hasConceptScore W4387473378C86381522 @default.
- W4387473378 hasLocation W43874733781 @default.
- W4387473378 hasLocation W43874733782 @default.
- W4387473378 hasOpenAccess W4387473378 @default.
- W4387473378 hasPrimaryLocation W43874733781 @default.
- W4387473378 hasRelatedWork W1987687114 @default.
- W4387473378 hasRelatedWork W2020322901 @default.
- W4387473378 hasRelatedWork W2020414767 @default.
- W4387473378 hasRelatedWork W2024503895 @default.
- W4387473378 hasRelatedWork W2048013059 @default.
- W4387473378 hasRelatedWork W2149528409 @default.
- W4387473378 hasRelatedWork W2735678415 @default.
- W4387473378 hasRelatedWork W2948997821 @default.
- W4387473378 hasRelatedWork W4242328659 @default.
- W4387473378 hasRelatedWork W4386488000 @default.
- W4387473378 isParatext "false" @default.
- W4387473378 isRetracted "false" @default.
- W4387473378 workType "article" @default.