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• W4387473403 abstract "We report the synthesis, characterization, and photoelectric and electrochemical properties of (CH3NH3)2Zn1-xCoxBr4 (x = 0.0, 0.3, 0.5, 0.7, and 1.0) samples. X-ray powder and single-crystal diffraction confirm the formation of solid solution across the entire range. Additionally, as the cobalt concentration increases, the crystallinity of the samples decreases, as indicated by the powder diffraction patterns. All samples remain stable up to 560 K, beyond which they decompose into CH3NH3Br and the respective bromide. The semiconductor behavior of the compounds is confirmed through optical absorption measurements, and band gap values are determined by using the Tauc method from diffuse reflectance spectra. Raman spectroscopy reveals a slight redshift in all vibration modes with increasing cobalt content. Finally, photovoltaic measurements on solar cells constructed with (MA)2CoBr4 perovskite exhibit modest performance, and electrochemical measurements indicate that the compound with the composition (MA)2Zn0.3Co0.7Br4 exhibits the highest current for electrochemical water reduction during oxygen evolution." @default.
• W4387473403 created "2023-10-11" @default.
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• W4387473403 date "2023-10-10" @default.
• W4387473403 modified "2023-10-16" @default.
• W4387473403 title "Synthesis, Characterization, and Photoelectric and Electrochemical Behavior of (CH₃NH₃)₂Zn_1–<i>x</i>Co_<i>x</i>Br₄ Perovskites" @default.
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• W4387473403 doi "https://doi.org/10.1021/acs.inorgchem.3c02574" @default.
• W4387473403 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37814970" @default.
• W4387473403 hasPublicationYear "2023" @default.
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