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- W4387478110 abstract "One of the key challenges of metallo-supramolecular chemistry is to maintain the ease of self-assembly but, at the same time, create structures of increasingly high levels of complexity. In palladium(II) quadruply-stranded lantern-shaped cages, this has been achieved through either 1) the formation of heteroleptic (multi-ligand) assemblies, or 2) homoleptic assemblies from low-symmetry ligands. Heteroleptic cages formed from low symmetry ligands. A hybid of these two approaches would add an additional rich level of complexity but no examples of these have been reported. Here we use a system of ancillary complementary ligand pairings at the termini of cage ligands to target heteroleptic assemblies: these complementary pairs can only interact (through coordination to a single Pd(II) metal ion) between ligands in a cis position on the cage. Complementarity between each pair (and orthogonality to other pairs) is controlled by denticity (tridentate to monodentate or bidentate to bidentate) and/or hydrogen bonding capability (AA to DD or AD to DA). This allows positional and orientational control over ligands with different ancillary sites. Using this approach, we have successfully used low-symmetry ligands to synthesise complex heteroleptic cages, including an example with four different low symmetry ligands." @default.
- W4387478110 created "2023-10-11" @default.
- W4387478110 creator A5017128684 @default.
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- W4387478110 date "2023-10-10" @default.
- W4387478110 modified "2023-10-12" @default.
- W4387478110 title "A Lantern‐Shaped Pd(II) Cage Constructed from Four Different Low Symmetry Ligands with Positional and Orientational Control: an Ancillary Pairings Approach" @default.
- W4387478110 doi "https://doi.org/10.1002/anie.202314378" @default.
- W4387478110 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37816684" @default.
- W4387478110 hasPublicationYear "2023" @default.
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