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• W4387489783 abstract "Phosphonocarboxylation of allenes with diarylphosphine oxides and CO2 via visible-light photoredox catalysis was developed for the first time. This work provided practical and sustainable access to highly valuable but otherwise difficult-to-access linear allylic β-phosphonyl carboxylic acids in moderate yields with exclusive regio- and stereoselectivity. This method was also characterized by step and atom economy and transition-metal free and mild conditions. Preliminary mechanistic studies suggested that allyl-methyl carbanion species are the key intermediates." @default.
• W4387489783 created "2023-10-11" @default.
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• W4387489783 date "2023-10-10" @default.
• W4387489783 modified "2023-10-12" @default.
• W4387489783 title "Photoredox-Catalyzed Phosphonocarboxylation of Allenes with Phosphine Oxides and CO₂" @default.
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• W4387489783 doi "https://doi.org/10.1021/acs.joc.3c01583" @default.
• W4387489783 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37816195" @default.
• W4387489783 hasPublicationYear "2023" @default.
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