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- W4387497466 abstract "Abstract A static method is employed to determine the solubilities of verapamil in supercritical carbon dioxide (SC-CO 2 ) at temperatures between 308 and 338 K and pressures between 12 and 30 MPa. The solubility of verapamil in SC-CO 2 expressed as mole fraction are in the range of 3.6 × 10 –6 to 7.14 × 10 –5 . Using four semi-empirical density-based models, the solubility data are correlated: Chrastil, Bartle, Kumar–Johnston (K–J), and Mendez-Santiago and Teja (MST), two equations of state (SRK and PC-SAFT EoS), expanded liquid models (modified Wilson's models), and regular solution model. The obtained results indicated that the regular solution and PC-SAFT models showed the most noteworthy exactness with AARD% of 1.68 and 7.45, respectively. The total heat, vaporization heat, and solvation heat of verapamil are calculated at 39.62, 60.03, and − 20.41 kJ/mol, respectively. Regarding the poor solubility of verapamil in SC-CO 2 , supercritical anti-solvent methods can be an appropriate choice to produce fine particles of this drug." @default.
- W4387497466 created "2023-10-11" @default.
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- W4387497466 date "2023-10-10" @default.
- W4387497466 modified "2023-10-13" @default.
- W4387497466 title "Solubility measurement of verapamil for the preparation of developed nanomedicines using supercritical fluid" @default.
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- W4387497466 doi "https://doi.org/10.1038/s41598-023-44280-7" @default.
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