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- W4387515892 abstract "Reaction of (6-Dipp)CuOtBu (6-Dipp = C{NDippCH2}2CH2, Dipp = 2,6-iPr2C6H3) with B2(OMe)4 provided access to (6-Dipp)CuB(OMe)2 via σ-bond metathesis. (6-Dipp)CuB(OMe)2 was characterised by NMR spectroscopy and X-ray crystallography and shown to be a monomeric acyclic boryl of copper. (6-Dipp)CuB(OMe)2 reacted with ethylene and diphenylacetylene to provide insertion compounds into the Cu-B bond which were characterised by NMR spectroscopy in both cases and X-ray crystallography in the latter. It was also competent in the rapid catalytic deoxygenation of CO2 in the presence of excess B2(OMe)4. Alongside π-insertion, (6-Dipp)CuB(OMe)2 reacted with LiNMe2 to provide a salt metathesis reaction at boron, giving (6-Dipp)CuB(OMe)NMe2, a second monomeric acyclic boryl, which also cuproborated diphenylacetylene. Computational interrogation validated these acyclic boryl species to be electronically similar to (6-Dipp)CuBpin." @default.
- W4387515892 created "2023-10-12" @default.
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- W4387515892 date "2023-10-11" @default.
- W4387515892 modified "2023-10-12" @default.
- W4387515892 title "Acyclic Boryl Complexes of Copper(I)" @default.
- W4387515892 doi "https://doi.org/10.1002/chem.202302704" @default.
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