Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387564535> ?p ?o ?g. }
- W4387564535 abstract "Herein, we disclose a simple strategy for the C-H alkylation of electron-rich (hetero)arenes with alkyl bromides employing visible-light-mediated organo-photocatalytic SET processes. The generality of this method has been evidenced by the inclusion of a variety of alkyl radicals (α-alkyl-carbonyl, benzyl, cyanomethyl) as well as diverse biologically active electron-rich arenes and (hetero)arenes under mild conditions. The extent of alkylation with alkyl bromides was found to be controlled by introducing Zn(OAc)2 as a bromide scavenger, ensuring the blocking of potential bromo-arene byproduct formation under photoredox conditions. In addition, a sequential C-H alkylation strategy for selective bis-alkylation has also been developed via chronological incorporation of different alkyl radical precursors in one pot quite efficiently." @default.
- W4387564535 created "2023-10-13" @default.
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- W4387564535 date "2023-10-12" @default.
- W4387564535 modified "2023-10-13" @default.
- W4387564535 title "Organo-photoredox-Catalyzed Selective Mono- and Bis-C–H Alkylation of Electron-Rich (Hetero)Arenes" @default.
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- W4387564535 doi "https://doi.org/10.1021/acs.joc.3c01757" @default.
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