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- W4387568561 abstract "α-Pyridyl tertiary amino acids have potential pharmaceutical applications because of their structural features. However, their synthesis is still highly limited. Herein, we report a straightforward approach for the electrochemical synthesis of tertiary α-substituted amino acid derivatives via three-component reductive coupling. Using gaseous ammonia as both the N and H source, the α-keto ester reacts directly with 4-CN-pyridine. The application of scandium catalysis is the key for achieving chemoselectivity among various side reaction pathways." @default.
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- W4387568561 date "2023-10-12" @default.
- W4387568561 modified "2023-10-14" @default.
- W4387568561 title "Scandium-Catalyzed Electrochemical Synthesis of α-Pyridinyl Tertiary Amino Acids and Esters" @default.
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- W4387568561 doi "https://doi.org/10.1021/acs.orglett.3c02734" @default.
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