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Matches in SemOpenAlex for { <https://semopenalex.org/work/W4387598706> ?p ?o ?g. }

• W4387598706 abstract "We report an enantioselective synthesis of cyclic ketones with full substitutions at the α-positions in a highly diastereoselective manner. Our method is achieved by subjecting substrate motifs in 2-allyloxyenones to chiral organomagnesium reagents, which trigger the Claisen rearrangement upon direct 1,2-carbonyl addition. The observed diastereoselectivity of the allyl migration is proposed to originate from the intramolecular chelation of the magnesium alkoxide to the allyloxy moiety." @default.
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• W4387598706 date "2023-10-13" @default.
• W4387598706 modified "2023-10-14" @default.
• W4387598706 title "Directing the Stereoselectivity of the Claisen Rearrangement to Form Cyclic Ketones with Full Substitution at the α-Positions" @default.
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• W4387598706 doi "https://doi.org/10.1021/acs.orglett.3c02752" @default.
• W4387598706 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37830497" @default.
• W4387598706 hasPublicationYear "2023" @default.
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