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- W4387605429 abstract "Super-reduction of polyoxometalates (POMs) in solution is of fundamental interest for designing innovative energy storage systems. In this article, we show that the Dawson-like POM can undergo a disproportionation process during its massive electron uptake, leading to species containing three metal-metal bonds as evidenced by X-ray diffraction, multi-nuclear magnetic resonance spectroscopy (1H and 183W NMR), extended X-ray absorption fine structure (EXAFS), UV-vis, and voltammetry techniques. This result indicates that electron storing within metal-metal bonds is not a unique property of Keggin-type POM as postulated since the 70s. Besides, we demonstrate that the presence of an electron-rich triad in the Dawson-like POM allows its post-functionalization with additional tungstate ions, generating a chiral molecule that is also the largest WIV-containing POMs known to date." @default.
- W4387605429 created "2023-10-14" @default.
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- W4387605429 date "2023-10-13" @default.
- W4387605429 modified "2023-10-15" @default.
- W4387605429 title "Clustering Six Electrons within “Dawson‐Like” Polyoxometalate: An Open Route toward Its Post‐functionalization" @default.
- W4387605429 doi "https://doi.org/10.1002/anie.202312457" @default.
- W4387605429 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37831589" @default.
- W4387605429 hasPublicationYear "2023" @default.
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