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- W4387661357 abstract "The dynamic covalent chemistry of imines is utilized to conduct a regioselective as well as enantioselective synthesis of an unsymmetric (C1) chiral macrocycle from the reaction of an unsymmetric (C1) chiral dialdehyde, (S)-4, that contains a salicylaldehyde unit and a benzaldehyde unit, with lysine, an unsymmetric (C1) chiral diamine. The enantioselectivity is further enhanced in the presence of Zn2+. Compound (S)-4 in combination with Zn2+ is found to be a highly chemoselective as well as enantioselective fluorescent probe for lysine. It can be used to detect specific enantiomers of this amino acid." @default.
- W4387661357 created "2023-10-17" @default.
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- W4387661357 date "2023-10-16" @default.
- W4387661357 modified "2023-10-17" @default.
- W4387661357 title "Regio- and Enantioselective Macrocyclization from Dynamic Imine Formation: Chemo- and Enantioselective Fluorescent Recognition of Lysine" @default.
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- W4387661357 doi "https://doi.org/10.1021/acs.orglett.3c02949" @default.
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