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- W4387675323 abstract "Aqueous ethanol mixtures of different percentage compositions were used as solvents for poorly water soluble drug aspirin. Densities of the solutions were measured experimentally at four different temperatures. Other volumetric parameters were derived from the density values in order to gather an insight on solute–solute and solute–solvent interactions existing in the ternary solutions. Positive values of apparent molar volume (V∅), limiting apparent molar volume (V∅0), apparent molar expansibility (E∅0) and isobaric thermal expansion coefficient (αp) reinforce the idea of strong solute–solvent interactions, structure making properties of aspirin and caging effect of the binary solvent existing in all the systems. Structure making properties of aspirin is further supported by Hepler’s constant. Occurrence of interactions between ionic, polar and nonpolar chain ends and segments in the solutions is established." @default.
- W4387675323 created "2023-10-17" @default.
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- W4387675323 date "2023-10-01" @default.
- W4387675323 modified "2023-10-17" @default.
- W4387675323 title "Exegesis of volumetric properties of aspirin in aqueous ethanol to predict solute–solute and solute–solvent interactions" @default.
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- W4387675323 doi "https://doi.org/10.1016/j.matpr.2023.10.076" @default.
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