Matches in SemOpenAlex for { <https://semopenalex.org/work/W44177615> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W44177615 abstract "The oxidn. of alanine and phenylalanine by chloramine-T (I) in HCl at 30° showed, at low acid concn. (0.04-0.10M), 1st-order kinetics each in I and H+ and 0-order in amino acid concn. Ionic strength and addn. of the reaction product, p-MeC6H4SO2NH2 (II), have no effect on the rate, but Cl- increases the rate of oxidn. At higher HCl concns. (0.16-0.35M), the rate shows 1st-order dependence on I and amino acid and is independent of H+. Ionic strength and addn. of II or NaCl have no effect on the rate, but a pos. MeOH effect is noted. Activation of parameters are given and a mechanism is described. [on SciFinder(R)]" @default.
- W44177615 created "2016-06-24" @default.
- W44177615 creator A5002301577 @default.
- W44177615 creator A5046850772 @default.
- W44177615 creator A5074839338 @default.
- W44177615 date "1980-04-01" @default.
- W44177615 modified "2023-10-11" @default.
- W44177615 title "Kinetics and mechanism of oxidation of alanine and phenylalanine by chloramine-T in acid medium." @default.
- W44177615 hasPublicationYear "1980" @default.
- W44177615 type Work @default.
- W44177615 sameAs 44177615 @default.
- W44177615 citedByCount "0" @default.
- W44177615 crossrefType "journal-article" @default.
- W44177615 hasAuthorship W44177615A5002301577 @default.
- W44177615 hasAuthorship W44177615A5046850772 @default.
- W44177615 hasAuthorship W44177615A5074839338 @default.
- W44177615 hasConcept C121332964 @default.
- W44177615 hasConcept C148898269 @default.
- W44177615 hasConcept C155647269 @default.
- W44177615 hasConcept C178790620 @default.
- W44177615 hasConcept C179104552 @default.
- W44177615 hasConcept C184651966 @default.
- W44177615 hasConcept C185592680 @default.
- W44177615 hasConcept C187428577 @default.
- W44177615 hasConcept C2777431362 @default.
- W44177615 hasConcept C2779488458 @default.
- W44177615 hasConcept C2779856020 @default.
- W44177615 hasConcept C2781060987 @default.
- W44177615 hasConcept C505241676 @default.
- W44177615 hasConcept C515207424 @default.
- W44177615 hasConcept C55493867 @default.
- W44177615 hasConcept C62520636 @default.
- W44177615 hasConceptScore W44177615C121332964 @default.
- W44177615 hasConceptScore W44177615C148898269 @default.
- W44177615 hasConceptScore W44177615C155647269 @default.
- W44177615 hasConceptScore W44177615C178790620 @default.
- W44177615 hasConceptScore W44177615C179104552 @default.
- W44177615 hasConceptScore W44177615C184651966 @default.
- W44177615 hasConceptScore W44177615C185592680 @default.
- W44177615 hasConceptScore W44177615C187428577 @default.
- W44177615 hasConceptScore W44177615C2777431362 @default.
- W44177615 hasConceptScore W44177615C2779488458 @default.
- W44177615 hasConceptScore W44177615C2779856020 @default.
- W44177615 hasConceptScore W44177615C2781060987 @default.
- W44177615 hasConceptScore W44177615C505241676 @default.
- W44177615 hasConceptScore W44177615C515207424 @default.
- W44177615 hasConceptScore W44177615C55493867 @default.
- W44177615 hasConceptScore W44177615C62520636 @default.
- W44177615 hasLocation W441776151 @default.
- W44177615 hasOpenAccess W44177615 @default.
- W44177615 hasPrimaryLocation W441776151 @default.
- W44177615 hasRelatedWork W1976311470 @default.
- W44177615 hasRelatedWork W1989355484 @default.
- W44177615 hasRelatedWork W1997775482 @default.
- W44177615 hasRelatedWork W2001870440 @default.
- W44177615 hasRelatedWork W2012399831 @default.
- W44177615 hasRelatedWork W2043726587 @default.
- W44177615 hasRelatedWork W2090221687 @default.
- W44177615 hasRelatedWork W2097777455 @default.
- W44177615 hasRelatedWork W2118043353 @default.
- W44177615 hasRelatedWork W2161971621 @default.
- W44177615 hasRelatedWork W2189458935 @default.
- W44177615 hasRelatedWork W2300037275 @default.
- W44177615 hasRelatedWork W2317672947 @default.
- W44177615 hasRelatedWork W253978530 @default.
- W44177615 hasRelatedWork W2790660750 @default.
- W44177615 hasRelatedWork W2952051365 @default.
- W44177615 hasRelatedWork W629967889 @default.
- W44177615 hasRelatedWork W75711061 @default.
- W44177615 hasRelatedWork W2189413958 @default.
- W44177615 hasRelatedWork W574843168 @default.
- W44177615 isParatext "false" @default.
- W44177615 isRetracted "false" @default.
- W44177615 magId "44177615" @default.
- W44177615 workType "article" @default.