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- W44235518 abstract "Publisher Summary This chapter discusses kinetics of the reaction of the two electron gate of photosystem II (PSII). Studies of the mechanism of the two-electron gate by which electrons are transferred form PS II to the plastoquinone (PQ) pool have shown that a number of inhibitors act by competing with PQ from the pool for a binding site at which it undergoes reduction by one electron. In a study discussed in the chapter, the titration curves were measured for inhibition by a series of alkyl HNQ homologues. In each case, a similar pattern of inhibition after one or two flashes was seen but inhibitory effectiveness increased with length of the alkyl chain. When values for I 50 were plotted on a logarithmic scale for a full range of alkyl chain lengths, the effectiveness of inhibition was proportional to chain length suggesting that partition into the lipid phase was an important parameter. The binding of UHNQ before the flash was assayed by observing the fraction of centers that showed an uninhibited rate of Q A – oxidation immediately after the flash." @default.
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- W44235518 date "1983-01-01" @default.
- W44235518 modified "2023-09-26" @default.
- W44235518 title "KINETICS OF THE REACTION OF THE TWO ELECTRON GATE OF PHOTOSYSTEM II: STUDIES OF THE COMPETITION BETWEEN PLASTOQUINONE AND INHIBITORS" @default.
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- W44235518 doi "https://doi.org/10.1016/b978-0-12-372360-4.50046-8" @default.
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