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- W44496572 abstract "The mononuclear, tetrahedral iron and cobalt complexes, FeCl2(Hhpp)2, I, and CoCl2(Hhpp)2, II, are readily formed by the reaction of the metal (II) chloride with Hhpp. Compound II crystallized as blue blocks in the space group Fdd2. The reaction of I with LiMe yielded the trinuclear complex Fe3Cl2(hpp)4, III, which crystallized as colorless blocks in the space group P21/n. A cobalt complex Co3Cl2(hpp)4, IV, analogous to III, was synthesized by the reaction of CoCl2 with Lihpp. Compound IV crystallized as blue blocks in the space group P21. Both III and IV have three four-coordinate metal centers and contain no metal–metal bonds, two metal atoms are each bound to one chlorine and three nitrogen atoms while the third one is bound to four nitrogen atoms." @default.
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- W44496572 date "1998-12-01" @default.
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- W44496572 title "Trinuclear complexes of four-coordinate iron and cobalt:" @default.
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