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- W44701155 abstract "The partial enthalpies of solution of hydrogen in thorium-hydrogen alloys with H/Th ratios ranging from 0 to 2 have been measured calorimetrically at 700 K. From these data we calculate the standard enthalpy of formation of ThH/sub 2/ at this temperature to be -34.8 kcal mol/sup -1/ with an estimated uncertainty of +- 0.2 kcal mol/sup -1/. This agrees well with values calculated by earlier investigators from plateau pressure equilbrium data. For several alloy compositions within the nearly stoichiometric phase ThH/sub 2/ the equilibrium pressures of hydrogen also were determined. Comparisons of the relative partial Gibbs energies of hydrogen obtained from these equilibrium pressures with corresponding enthalpies from calorimetry provide information on the partial entropy. The partial enthalpy and entropy both change dramatically with composition between H/Th = 1.99 and 2.003." @default.
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- W44701155 date "1980-06-01" @default.
- W44701155 modified "2023-09-24" @default.
- W44701155 title "Thermodynamic study of the thorium-hydrogen system at 700 K" @default.
- W44701155 hasPublicationYear "1980" @default.
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