Matches in SemOpenAlex for { <https://semopenalex.org/work/W4523780> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W4523780 endingPage "982" @default.
- W4523780 startingPage "978" @default.
- W4523780 abstract "Controlled heating of single crystals of the previously reported [Köferstein & Robl (2007). Z. Anorg. Allg. Chem. 633 , 1127–1130] dihydrate {[Co(pht)(bpy)(H 2 O) 2 ]·2H 2 O} n , (II) [where pht is phthalate (C 8 H 4 O 4 ) and bpy is 4,4′-bipyridine (C 10 H 8 N 2 )], produced a topotactic transformation into an unreported diaqua anhydrate, namely poly[diaqua(μ 2 -benzene-1,2-dicarboxylato-κ 2 O 1 : O 2 )(μ 2 -4,4′-bipyridine-κ 2 N : N ′)cobalt(II)], [Co(C 8 H 4 O 4 )(C 10 H 8 N 2 )(H 2 O) 2 ] n , (II a ). The structural change consists of the loss of the two solvent water molecules linking the original two-dimensional covalent substructures which are the `main frame' of the monoclinic P 2/ n hydrate (strictly preserved during the transformation), with further reaccommodation of the latter. The anhydrate organizes itself in the orthorhombic system (space group Pmn 2 1 ) in a disordered fashion, where the space-group-symmetry restrictions are achieved only in a statistical sense, with mirror-related two-dimensional planar substructures, mirrored in a plane perpendicular to [100]. Thus, the asymmetric unit in the refined model is composed of two superimposed mirror-related `ghosts' of half-occupancy each. Similarities and differences with the parent dihydrate and some other related structures in the literature are discussed." @default.
- W4523780 created "2016-06-24" @default.
- W4523780 creator A5027179747 @default.
- W4523780 creator A5057336452 @default.
- W4523780 creator A5060885391 @default.
- W4523780 creator A5082289524 @default.
- W4523780 date "2014-09-28" @default.
- W4523780 modified "2023-10-18" @default.
- W4523780 title "The topotactic dehydration of monoclinic {[Co(pht)(bpy)(H2O)2]·2H2O}ninto orthorhombic [Co(pht)(bpy)(H2O)2]n(pht is phthalate and bpy is 4,4′-bipyridine)" @default.
- W4523780 cites W1975211801 @default.
- W4523780 cites W2012529181 @default.
- W4523780 cites W2015616422 @default.
- W4523780 cites W2032842297 @default.
- W4523780 cites W2051426975 @default.
- W4523780 cites W2128179591 @default.
- W4523780 cites W2131350133 @default.
- W4523780 cites W2145538332 @default.
- W4523780 doi "https://doi.org/10.1107/s2053229614020427" @default.
- W4523780 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25279600" @default.
- W4523780 hasPublicationYear "2014" @default.
- W4523780 type Work @default.
- W4523780 sameAs 4523780 @default.
- W4523780 citedByCount "3" @default.
- W4523780 countsByYear W45237802015 @default.
- W4523780 countsByYear W45237802017 @default.
- W4523780 countsByYear W45237802019 @default.
- W4523780 crossrefType "journal-article" @default.
- W4523780 hasAuthorship W4523780A5027179747 @default.
- W4523780 hasAuthorship W4523780A5057336452 @default.
- W4523780 hasAuthorship W4523780A5060885391 @default.
- W4523780 hasAuthorship W4523780A5082289524 @default.
- W4523780 hasBestOaLocation W45237802 @default.
- W4523780 hasConcept C112887158 @default.
- W4523780 hasConcept C115624301 @default.
- W4523780 hasConcept C178790620 @default.
- W4523780 hasConcept C185592680 @default.
- W4523780 hasConcept C2777981386 @default.
- W4523780 hasConcept C2779336533 @default.
- W4523780 hasConcept C2781002295 @default.
- W4523780 hasConcept C2781060337 @default.
- W4523780 hasConcept C32909587 @default.
- W4523780 hasConcept C37243968 @default.
- W4523780 hasConcept C61276311 @default.
- W4523780 hasConcept C71240020 @default.
- W4523780 hasConcept C8010536 @default.
- W4523780 hasConceptScore W4523780C112887158 @default.
- W4523780 hasConceptScore W4523780C115624301 @default.
- W4523780 hasConceptScore W4523780C178790620 @default.
- W4523780 hasConceptScore W4523780C185592680 @default.
- W4523780 hasConceptScore W4523780C2777981386 @default.
- W4523780 hasConceptScore W4523780C2779336533 @default.
- W4523780 hasConceptScore W4523780C2781002295 @default.
- W4523780 hasConceptScore W4523780C2781060337 @default.
- W4523780 hasConceptScore W4523780C32909587 @default.
- W4523780 hasConceptScore W4523780C37243968 @default.
- W4523780 hasConceptScore W4523780C61276311 @default.
- W4523780 hasConceptScore W4523780C71240020 @default.
- W4523780 hasConceptScore W4523780C8010536 @default.
- W4523780 hasIssue "10" @default.
- W4523780 hasLocation W45237801 @default.
- W4523780 hasLocation W45237802 @default.
- W4523780 hasLocation W45237803 @default.
- W4523780 hasOpenAccess W4523780 @default.
- W4523780 hasPrimaryLocation W45237801 @default.
- W4523780 hasRelatedWork W1991650258 @default.
- W4523780 hasRelatedWork W2005058232 @default.
- W4523780 hasRelatedWork W2006632187 @default.
- W4523780 hasRelatedWork W2010543690 @default.
- W4523780 hasRelatedWork W2053657974 @default.
- W4523780 hasRelatedWork W2107892346 @default.
- W4523780 hasRelatedWork W2385674973 @default.
- W4523780 hasRelatedWork W2902603126 @default.
- W4523780 hasRelatedWork W2958005169 @default.
- W4523780 hasRelatedWork W4523780 @default.
- W4523780 hasVolume "70" @default.
- W4523780 isParatext "false" @default.
- W4523780 isRetracted "false" @default.
- W4523780 magId "4523780" @default.
- W4523780 workType "article" @default.