Matches in SemOpenAlex for { <https://semopenalex.org/work/W454633369> ?p ?o ?g. }
Showing items 1 to 41 of
41
with 100 items per page.
- W454633369 abstract "Bu calismada, N-benzil-4-nitrosalisilaldimin (IX), N-benzil-3, 5-dinitrosalisilaldimin (X), N-benzilsalisilaldi- min (XI) ve N-fenilsalisilaldimin (XII) Schiff bazlarinin birinci sira gecis elementlerinden Cu(II), Co(II), Ni(II) ve Mn(II) katyonlariyla verdikleri komplekslerin % 75 di- oksan-su ortaminda basamakli ve toplam kararlilik sabitleri tayin edilmistir. Tayinlerde Bjerrum'un potansiyometrik me todu kullanilmis ve n ile pL arasindaki bagintidan cizilen kompleks tesekkul egrilerinden yararlanilmistir. Bu sabit ler uzerine katyonlarin etkisi incelenmis ve komplekslerin toplam kararlilik sabitleri sirasinin katyonlara gore degi simi Cu(II) >Co(II) >Ni(II) >Mn(II) seklinde bulunmustur.Abstract In this work, the stepwise and overall stability constants of Cu(II), Co(II), Ni(II) and Mn(II) complexes with N-benzyl-H-nitrosalicylaldimine (IX), N-benzyl-3,5- dinitrosalicylaldimine (X), N-benzylsalicylaldimine (XI) and N-phenylsalicylaldimine (XII) have been determined in 7 5 percent dioxane/water solvents system. In the determina tions of the constants, the formation curves of the complexes betweeen n and pL values have been drawn by using the Bjerrum' potentiometric method. The effects of the cations on the sta bility constants have been discussed and the order of the overall stability constants of the metal complexes has been found to be as follows: Cu(II) >Co(II) > Ni(II) > Mn(II)" @default.
- W454633369 created "2016-06-24" @default.
- W454633369 creator A5023242849 @default.
- W454633369 creator A5046706848 @default.
- W454633369 date "1988-01-01" @default.
- W454633369 modified "2023-09-23" @default.
- W454633369 title "Schiff bazları ve bunların geçiş elementleriyle verdikleri komplekslerin dissosiyasyon sabitlerinin tayini" @default.
- W454633369 hasPublicationYear "1988" @default.
- W454633369 type Work @default.
- W454633369 sameAs 454633369 @default.
- W454633369 citedByCount "0" @default.
- W454633369 crossrefType "dissertation" @default.
- W454633369 hasAuthorship W454633369A5023242849 @default.
- W454633369 hasAuthorship W454633369A5046706848 @default.
- W454633369 hasConcept C13965031 @default.
- W454633369 hasConcept C147789679 @default.
- W454633369 hasConcept C155647269 @default.
- W454633369 hasConcept C161790260 @default.
- W454633369 hasConcept C168191866 @default.
- W454633369 hasConcept C178790620 @default.
- W454633369 hasConcept C184651966 @default.
- W454633369 hasConcept C185592680 @default.
- W454633369 hasConcept C2776455741 @default.
- W454633369 hasConcept C544153396 @default.
- W454633369 hasConceptScore W454633369C13965031 @default.
- W454633369 hasConceptScore W454633369C147789679 @default.
- W454633369 hasConceptScore W454633369C155647269 @default.
- W454633369 hasConceptScore W454633369C161790260 @default.
- W454633369 hasConceptScore W454633369C168191866 @default.
- W454633369 hasConceptScore W454633369C178790620 @default.
- W454633369 hasConceptScore W454633369C184651966 @default.
- W454633369 hasConceptScore W454633369C185592680 @default.
- W454633369 hasConceptScore W454633369C2776455741 @default.
- W454633369 hasConceptScore W454633369C544153396 @default.
- W454633369 hasLocation W4546333691 @default.
- W454633369 hasOpenAccess W454633369 @default.
- W454633369 hasPrimaryLocation W4546333691 @default.
- W454633369 isParatext "false" @default.
- W454633369 isRetracted "false" @default.
- W454633369 magId "454633369" @default.
- W454633369 workType "dissertation" @default.