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- W454712 abstract "Abstract Hydrogenation of ethylene over Pt/Al 2 O 3 catalysts has been studied under steady-state reaction condition with a simplified dynamic model. Reaction of reversibly adsorbed ethylene on catalyst support with spillover hydrogen was found to contribute a large portion to the overall reaction. Modification of the support by diazomethane to remove surface hydroxyl groups diminished significantly the reaction on support surface. Competitive adsorption between ethylene and acetylene indicated that diazomethane modification eliminated the adsorptive sites on the interface of metal and support that might act as the bridge for spillover hydrogen." @default.
- W454712 created "2016-06-24" @default.
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- W454712 date "1993-01-01" @default.
- W454712 modified "2023-09-25" @default.
- W454712 title "Influence of support modification on hydrogen spillover in ethylene hydrogenation over Pt/Al2O3 Catalyst" @default.
- W454712 doi "https://doi.org/10.1016/s0167-2991(08)63194-8" @default.
- W454712 hasPublicationYear "1993" @default.
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