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- W45560979 abstract "The title compound, (C6H16N)[Fe3(CH3CO2)8O(H2O)]·C7H8, was serendipitously crystallized from a reaction of disilanol with iron(II) acetate. The trinuclear acetatoferrate(III) anion has a triethylammonium cation as the counterion. The three Fe atoms lie on the vertices of a regular triangle and are octahedrally coordinated. The complete coordination of the anion includes shared ligands among the three metal ions: a central tribridging O atom and six bidentate bridging acetyl groups. The six-coordinations of two of the metal ions are completed by a monodentate acetate ligand, whereas that of the third metal ion is completed by a water molecule. The uncoordinated triethylammonium cation is involved in N—H⋯O hydrogen bonding to a singly coordinated acetyl group. The coordinated aqua molecule is involved in bifurcated O—H⋯O hydrogen bonding. C—H⋯O interactions are also observed. The toluene solvent molecule is disordered over two sets of sites in a 0.609 (11):0.391 (11) ratio." @default.
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- W45560979 date "2011-07-13" @default.
- W45560979 modified "2023-09-23" @default.
- W45560979 title "Triethylammonium hexa-μ<sub>2</sub>-acetato-κ<sup>12</sup><i>O</i>:<i>O</i>′-diacetato-κ<sup>2</sup><i>O</i>-aqua-μ<sub>3</sub>-oxido-triferrate(III) toluene monosolvate" @default.
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- W45560979 doi "https://doi.org/10.1107/s160053681102616x" @default.
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