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- W45593682 abstract "Magnetic properties of divided nickel catalysts prepared by reduction at various temperatures of unsupported, supported on silica, and antigorite precursors have been investigated in magnetic fields up to 70 kOe. Saturation magnetization is found to be nearly equal to that of bulk nickel. It is concluded (i) that studied samples are probably completely reduced, (ii) magnetic surface moments are equal to bulk ones, (iii) and that reduction of the silica support and Ni-Si alloy formation is unlikely. Adsorption and catalytic studies suggest that nickel catalysts reduced at high temperatures have (111) surface planes, on which adsorbed hydrogen could be partly bonded to several metallic atoms and which exhibit low activity with respect to hydrocarbons conversions (ethane hydrogenolysis and benzene hydrogenation)." @default.
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- W45593682 date "1980-01-01" @default.
- W45593682 modified "2023-09-27" @default.
- W45593682 title "Surface and Chemisorption Properties of Small Nickel Particles as Studied by High Field Magnetic Methods, and Catalytic Activity with Respect to Ethane Hydrogenolysis and Benzene Hydrogenation." @default.
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- W45593682 doi "https://doi.org/10.1016/s0167-2991(08)65202-7" @default.
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